New dirhodium(II,II) carboxylates with 2,6-bis(N′-1,2,4-triazolyl)pyridinato ligand (btp)

Youngmee Kim; Sung Jin Kim; Alan J. Lough

doi:10.1016/S0277-5387(01)00919-6

New dirhodium(II,II) carboxylates with 2,6-bis(N′-1,2,4-triazolyl)pyridinato ligand (btp)

Youngmee Kim, Sung Jin Kim, Alan J. Lough

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The structures of compounds containing Rh₂(O₂CR₃)₄ (R = CH₃ 1, C₆H₅ 2, and CF₃ 3) units and btp ligands have been determined. In both the compounds 1 and 2, dirhodium(II,II) acetate and dirhodium(II,II) benzoate are bridged by btp ligands to form one-dimensional chains. For compound 1, the Rh-Rh bond distance is 2.3869(9) Å and Rh-N(btp) bond distances are 2.23(2) and 2.26(2) Å. For compound 2, the Rh-Rh and Rh-N(btp) bond distances are 2.4037(9) and 2.272(4) Å, respectively. For compound 3, dirhodium(II,II) trifiuoroacetate creates a supermolecule of two fused rings in which one dirhodium(II,II) unit of the outer ring has the typical coordination of dirhodium(II,II) carboxylates, but the other unit of the inner ring has two bidentate CF₃COO^- ligands, two monodentate CF₃COO^- ligands and two monodentate btp ligands. The outer Rh-Rh and inner Rh-Rh distances are 2.4196(9) and 2.5651(9) Å, respectively.

Original language	English
Pages (from-to)	3073-3078
Number of pages	6
Journal	Polyhedron
Volume	20
Issue number	26-27
DOIs	https://doi.org/10.1016/S0277-5387(01)00919-6
State	Published - 1 Dec 2001

Bibliographical note

Funding Information:
Financial support from the Basic Research Program of the Korean Science & Engineering Foundation (Grant no. R05-2000-00002) is gratefully acknowledged.

Keywords

Crystal structures
Dinuclear complexes
One-dimensional polymers
Rhodium(II) complexes
Trifluoroacetate

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10.1016/S0277-5387(01)00919-6

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title = "New dirhodium(II,II) carboxylates with 2,6-bis(N′-1,2,4-triazolyl)pyridinato ligand (btp)",

abstract = "The structures of compounds containing Rh2(O2CR3)4 (R = CH3 1, C6H5 2, and CF3 3) units and btp ligands have been determined. In both the compounds 1 and 2, dirhodium(II,II) acetate and dirhodium(II,II) benzoate are bridged by btp ligands to form one-dimensional chains. For compound 1, the Rh-Rh bond distance is 2.3869(9) {\AA} and Rh-N(btp) bond distances are 2.23(2) and 2.26(2) {\AA}. For compound 2, the Rh-Rh and Rh-N(btp) bond distances are 2.4037(9) and 2.272(4) {\AA}, respectively. For compound 3, dirhodium(II,II) trifiuoroacetate creates a supermolecule of two fused rings in which one dirhodium(II,II) unit of the outer ring has the typical coordination of dirhodium(II,II) carboxylates, but the other unit of the inner ring has two bidentate CF3COO- ligands, two monodentate CF3COO- ligands and two monodentate btp ligands. The outer Rh-Rh and inner Rh-Rh distances are 2.4196(9) and 2.5651(9) {\AA}, respectively.",

keywords = "Crystal structures, Dinuclear complexes, One-dimensional polymers, Rhodium(II) complexes, Trifluoroacetate",

author = "Youngmee Kim and Kim, {Sung Jin} and Lough, {Alan J.}",

note = "Funding Information: Financial support from the Basic Research Program of the Korean Science & Engineering Foundation (Grant no. R05-2000-00002) is gratefully acknowledged.",

year = "2001",

month = dec,

day = "1",

doi = "10.1016/S0277-5387(01)00919-6",

language = "English",

volume = "20",

pages = "3073--3078",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "26-27",

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TY - JOUR

T1 - New dirhodium(II,II) carboxylates with 2,6-bis(N′-1,2,4-triazolyl)pyridinato ligand (btp)

AU - Kim, Youngmee

AU - Kim, Sung Jin

AU - Lough, Alan J.

N1 - Funding Information: Financial support from the Basic Research Program of the Korean Science & Engineering Foundation (Grant no. R05-2000-00002) is gratefully acknowledged.

PY - 2001/12/1

Y1 - 2001/12/1

N2 - The structures of compounds containing Rh2(O2CR3)4 (R = CH3 1, C6H5 2, and CF3 3) units and btp ligands have been determined. In both the compounds 1 and 2, dirhodium(II,II) acetate and dirhodium(II,II) benzoate are bridged by btp ligands to form one-dimensional chains. For compound 1, the Rh-Rh bond distance is 2.3869(9) Å and Rh-N(btp) bond distances are 2.23(2) and 2.26(2) Å. For compound 2, the Rh-Rh and Rh-N(btp) bond distances are 2.4037(9) and 2.272(4) Å, respectively. For compound 3, dirhodium(II,II) trifiuoroacetate creates a supermolecule of two fused rings in which one dirhodium(II,II) unit of the outer ring has the typical coordination of dirhodium(II,II) carboxylates, but the other unit of the inner ring has two bidentate CF3COO- ligands, two monodentate CF3COO- ligands and two monodentate btp ligands. The outer Rh-Rh and inner Rh-Rh distances are 2.4196(9) and 2.5651(9) Å, respectively.

AB - The structures of compounds containing Rh2(O2CR3)4 (R = CH3 1, C6H5 2, and CF3 3) units and btp ligands have been determined. In both the compounds 1 and 2, dirhodium(II,II) acetate and dirhodium(II,II) benzoate are bridged by btp ligands to form one-dimensional chains. For compound 1, the Rh-Rh bond distance is 2.3869(9) Å and Rh-N(btp) bond distances are 2.23(2) and 2.26(2) Å. For compound 2, the Rh-Rh and Rh-N(btp) bond distances are 2.4037(9) and 2.272(4) Å, respectively. For compound 3, dirhodium(II,II) trifiuoroacetate creates a supermolecule of two fused rings in which one dirhodium(II,II) unit of the outer ring has the typical coordination of dirhodium(II,II) carboxylates, but the other unit of the inner ring has two bidentate CF3COO- ligands, two monodentate CF3COO- ligands and two monodentate btp ligands. The outer Rh-Rh and inner Rh-Rh distances are 2.4196(9) and 2.5651(9) Å, respectively.

KW - Crystal structures

KW - Dinuclear complexes

KW - One-dimensional polymers

KW - Rhodium(II) complexes

KW - Trifluoroacetate

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U2 - 10.1016/S0277-5387(01)00919-6

DO - 10.1016/S0277-5387(01)00919-6

M3 - Article

AN - SCOPUS:0035585860

SN - 0277-5387

VL - 20

SP - 3073

EP - 3078

JO - Polyhedron

JF - Polyhedron

IS - 26-27

ER -

New dirhodium(II,II) carboxylates with 2,6-bis(N′-1,2,4-triazolyl)pyridinato ligand (btp)

Abstract

Bibliographical note

Keywords

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