Nano-sized particles of Prussian blue analogue KxCo y[Fe(CN)6] and KxNiy[Fe(CN) 6]: Synthesis and their properties

Nguyen Van Minh; Phung Kim Phu; In Sang Yang

doi:10.3938/jkps.53.3559

Nano-sized particles of Prussian blue analogue K_xCo _y[Fe(CN)₆] and K_xNi_y[Fe(CN) ₆]: Synthesis and their properties

Nguyen Van Minh, Phung Kim Phu, In Sang Yang

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Recently, striking effects of light irradiation on the magnetic state were reported for Prussian blue analogues A_xCo_y[Fe(CN) ₆] (A = Na, K, Rb, Cs). The physical and optical properties are dependent on the size of the particles of the measured samples. However, there have been few report on the formation of nano-sized particles of the material and the effect of size of the particles on the properties of the compounds. In this report, we investigate the effect of size of the particles on the properties of the Prussian blue analogue K_xCo_y[Fe(CN) ₆] and K_xNi_y[Fe(CN)₆]. We present a novel synthesis method of the K_xCo_y[Fe(CN)₆] and K_xNi_y[Fe(CN)₆] nano-particles. The results of the X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis absorption and magnetization measurements of the compounds are presented.

Original language	English
Pages (from-to)	3559-3562
Number of pages	4
Journal	Journal of the Korean Physical Society
Volume	53
Issue number	6 PART 1
DOIs	https://doi.org/10.3938/jkps.53.3559
State	Published - Dec 2008

Keywords

Magnetic property
Nanoparticle
Prussian blue
Size effect

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10.3938/jkps.53.3559

Cite this

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title = "Nano-sized particles of Prussian blue analogue KxCo y[Fe(CN)6] and KxNiy[Fe(CN) 6]: Synthesis and their properties",

abstract = "Recently, striking effects of light irradiation on the magnetic state were reported for Prussian blue analogues AxCoy[Fe(CN) 6] (A = Na, K, Rb, Cs). The physical and optical properties are dependent on the size of the particles of the measured samples. However, there have been few report on the formation of nano-sized particles of the material and the effect of size of the particles on the properties of the compounds. In this report, we investigate the effect of size of the particles on the properties of the Prussian blue analogue KxCoy[Fe(CN) 6] and KxNiy[Fe(CN)6]. We present a novel synthesis method of the KxCoy[Fe(CN)6] and KxNiy[Fe(CN)6] nano-particles. The results of the X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis absorption and magnetization measurements of the compounds are presented.",

keywords = "Magnetic property, Nanoparticle, Prussian blue, Size effect",

author = "{Van Minh}, Nguyen and Phu, {Phung Kim} and Yang, {In Sang}",

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T1 - Nano-sized particles of Prussian blue analogue KxCo y[Fe(CN)6] and KxNiy[Fe(CN) 6]

T2 - Synthesis and their properties

AU - Van Minh, Nguyen

AU - Phu, Phung Kim

AU - Yang, In Sang

PY - 2008/12

Y1 - 2008/12

N2 - Recently, striking effects of light irradiation on the magnetic state were reported for Prussian blue analogues AxCoy[Fe(CN) 6] (A = Na, K, Rb, Cs). The physical and optical properties are dependent on the size of the particles of the measured samples. However, there have been few report on the formation of nano-sized particles of the material and the effect of size of the particles on the properties of the compounds. In this report, we investigate the effect of size of the particles on the properties of the Prussian blue analogue KxCoy[Fe(CN) 6] and KxNiy[Fe(CN)6]. We present a novel synthesis method of the KxCoy[Fe(CN)6] and KxNiy[Fe(CN)6] nano-particles. The results of the X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis absorption and magnetization measurements of the compounds are presented.

AB - Recently, striking effects of light irradiation on the magnetic state were reported for Prussian blue analogues AxCoy[Fe(CN) 6] (A = Na, K, Rb, Cs). The physical and optical properties are dependent on the size of the particles of the measured samples. However, there have been few report on the formation of nano-sized particles of the material and the effect of size of the particles on the properties of the compounds. In this report, we investigate the effect of size of the particles on the properties of the Prussian blue analogue KxCoy[Fe(CN) 6] and KxNiy[Fe(CN)6]. We present a novel synthesis method of the KxCoy[Fe(CN)6] and KxNiy[Fe(CN)6] nano-particles. The results of the X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis absorption and magnetization measurements of the compounds are presented.

KW - Magnetic property

KW - Nanoparticle

KW - Prussian blue

KW - Size effect

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