Multiple electron & phonon scattering effect achieves highly efficient thermoelectricity due to nanostructuring

Junphil Hwang, Jae Hyun Yun, Kwan Young Lee, Jong Soo Rhyee, Jungwon Kim, Somnath Acharya, Jiyong Kim, Woochul Kim, Sujin Kim, Sung Jin Kim

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

To enhance the thermoelectric efficiency of a material, the decoupling of transport parameters in the dimensionless figure of merit, zT is important. The SnTe with MnTe magnetic nanoprecipitates was synthesized resulting in a high figure of merit. The gigantic localized spin moment of MnTe nanoprecipitates effectively scatters the conduction electron in SnTe, decoupling Seebeck coefficient, S, and electrical conductivity, σ. As a result, the powerfactor, S2σ was enhanced dramatically over the entire temperature range. The localized spin moment of MnTe nanoprecipitates was significantly larger than that of conventional magnetic atomic substitution in the alloy. Therefore, the spin moment fluctuation of superparamagnetic nanoprecipitates could effectively scatter electrons even at a high temperature. The first quantitative theoretical analysis for electron scattering was conducted in this work, to verify the spin dependent scattering. The weak localization measurement also supported the enhanced electron scattering by localized spin moment. The coherent MnTe nanoprecipitates in the SnTe matrix also reduced lattice thermal conductivity significantly. The slight difference in the lattice parameter between matrix SnTe and precipitates MnTe induced lattice strain and enhanced phonon scattering. The thermoelectric figure of merit zT was recorded 1.8 at 923 K in the eco-friendly material.

Original languageEnglish
Article number101053
JournalMaterials Today Physics
Volume33
DOIs
StatePublished - Apr 2023

Bibliographical note

Funding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( 2021R1A6A1A10039823 ). This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government( MSIT ) ( NRF-2021R1A2C2091348 ). This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( 2021R1I1A1A01058838 ).

Publisher Copyright:
© 2023 The Author(s)

Keywords

  • Electron spin
  • Kondo effect
  • Magnetism
  • Phonon scattering
  • Thermoelectric

Fingerprint

Dive into the research topics of 'Multiple electron & phonon scattering effect achieves highly efficient thermoelectricity due to nanostructuring'. Together they form a unique fingerprint.

Cite this