Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation

Dong Youn Noh; Ha Jin Lee; Haeyong Kang; Woun Kang; Uk Lee

doi:10.1080/10587250210737

Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation

Dong Youn Noh, Ha Jin Lee, Haeyong Kang, Woun Kang, Uk Lee

Department of Physics

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

Nickel-bisdithiolate complexes with a ferrocene-containing 2nd order nonlinear optical chromophore as a cation, (FcCH=CHPyMe)[NiL₂] where L = dmit (1a), dddt (1b) and debt (1c) were synthesized by the cation exchange reaction. In the X-ray crystal structure of complex (1a), no intrastack but interstack S...S interactions less than 3.7 Å are observed. This complex was revealed to be an insulator at room temperature. However, (FcCH=CHPyMe) _x[Ni(dmit)₂] (0 < x < 1) (3) needle grown in an H-type electrochemical cell shows semiconductor behavior (E_a =106 meV) over the temperature range measured (30 ∼300 K) with σ_RT = 1 Ω^-1cm^-1. The electronic transition at UV-vis-NIR region was measured for the nickel complexes and discussed.

Original language	English
Pages (from-to)	269-274
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	376
DOIs	https://doi.org/10.1080/10587250210737
State	Published - 2002
Event	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States Duration: 15 Dec 2000 → 18 Dec 2000

Keywords

2nd order NLO chromophore
Electrical conductivity
Nickel-bisdithiolate
UV-vis-NIR absorption

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10.1080/10587250210737

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@article{281b4e0527694f75a0fb9cb3696a8a6c,

title = "Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation",

abstract = "Nickel-bisdithiolate complexes with a ferrocene-containing 2nd order nonlinear optical chromophore as a cation, (FcCH=CHPyMe)[NiL2] where L = dmit (1a), dddt (1b) and debt (1c) were synthesized by the cation exchange reaction. In the X-ray crystal structure of complex (1a), no intrastack but interstack S...S interactions less than 3.7 {\AA} are observed. This complex was revealed to be an insulator at room temperature. However, (FcCH=CHPyMe) x[Ni(dmit)2] (0 < x < 1) (3) needle grown in an H-type electrochemical cell shows semiconductor behavior (Ea =106 meV) over the temperature range measured (30 ∼300 K) with σRT = 1 Ω-1cm-1. The electronic transition at UV-vis-NIR region was measured for the nickel complexes and discussed.",

keywords = "2nd order NLO chromophore, Electrical conductivity, Nickel-bisdithiolate, UV-vis-NIR absorption",

author = "Noh, {Dong Youn} and Lee, {Ha Jin} and Haeyong Kang and Woun Kang and Uk Lee",

year = "2002",

doi = "10.1080/10587250210737",

language = "English",

volume = "376",

pages = "269--274",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

note = "Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids ; Conference date: 15-12-2000 Through 18-12-2000",

}

Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation. / Noh, Dong Youn; Lee, Ha Jin; Kang, Haeyong et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 376, 2002, p. 269-274.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation

AU - Noh, Dong Youn

AU - Lee, Ha Jin

AU - Kang, Haeyong

AU - Kang, Woun

AU - Lee, Uk

PY - 2002

Y1 - 2002

N2 - Nickel-bisdithiolate complexes with a ferrocene-containing 2nd order nonlinear optical chromophore as a cation, (FcCH=CHPyMe)[NiL2] where L = dmit (1a), dddt (1b) and debt (1c) were synthesized by the cation exchange reaction. In the X-ray crystal structure of complex (1a), no intrastack but interstack S...S interactions less than 3.7 Å are observed. This complex was revealed to be an insulator at room temperature. However, (FcCH=CHPyMe) x[Ni(dmit)2] (0 < x < 1) (3) needle grown in an H-type electrochemical cell shows semiconductor behavior (Ea =106 meV) over the temperature range measured (30 ∼300 K) with σRT = 1 Ω-1cm-1. The electronic transition at UV-vis-NIR region was measured for the nickel complexes and discussed.

AB - Nickel-bisdithiolate complexes with a ferrocene-containing 2nd order nonlinear optical chromophore as a cation, (FcCH=CHPyMe)[NiL2] where L = dmit (1a), dddt (1b) and debt (1c) were synthesized by the cation exchange reaction. In the X-ray crystal structure of complex (1a), no intrastack but interstack S...S interactions less than 3.7 Å are observed. This complex was revealed to be an insulator at room temperature. However, (FcCH=CHPyMe) x[Ni(dmit)2] (0 < x < 1) (3) needle grown in an H-type electrochemical cell shows semiconductor behavior (Ea =106 meV) over the temperature range measured (30 ∼300 K) with σRT = 1 Ω-1cm-1. The electronic transition at UV-vis-NIR region was measured for the nickel complexes and discussed.

KW - 2nd order NLO chromophore

KW - Electrical conductivity

KW - Nickel-bisdithiolate

KW - UV-vis-NIR absorption

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DO - 10.1080/10587250210737

M3 - Conference article

AN - SCOPUS:8644240298

SN - 1058-725X

VL - 376

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JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

T2 - Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids

Y2 - 15 December 2000 through 18 December 2000

ER -

Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation

Abstract

Keywords

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