Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Junying Chen; Kyung Bin Cho; Yong Min Lee; Yoon Hye Kwon; Wonwoo Nam

doi:10.1039/c5cc04217h

Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Junying Chen, Kyung Bin Cho, Yong Min Lee, Yoon Hye Kwon, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [M^IVO(N4Py)]²⁺ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that Fe^IVO is more reactive than Mn^IVO. The latter is shown to react through excited state reactivity (ESR).

Original language	English
Pages (from-to)	13094-13097
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	66
DOIs	https://doi.org/10.1039/c5cc04217h
State	Published - 25 Aug 2015

Bibliographical note

Publisher Copyright:
© 2015 The Royal Society of Chemistry.

Access to Document

10.1039/c5cc04217h

Cite this

@article{c82bc1c4930f4f6f926e582dc9e79c3c,

title = "Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction",

abstract = "Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).",

author = "Junying Chen and Cho, \{Kyung Bin\} and Lee, \{Yong Min\} and Kwon, \{Yoon Hye\} and Wonwoo Nam",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "25",

doi = "10.1039/c5cc04217h",

language = "English",

volume = "51",

pages = "13094--13097",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "66",

}

TY - JOUR

T1 - Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions

T2 - Experimental results prove theoretical prediction

AU - Chen, Junying

AU - Cho, Kyung Bin

AU - Lee, Yong Min

AU - Kwon, Yoon Hye

AU - Nam, Wonwoo

PY - 2015/8/25

Y1 - 2015/8/25

N2 - Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).

AB - Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).

UR - https://www.scopus.com/pages/publications/84938844275

U2 - 10.1039/c5cc04217h

DO - 10.1039/c5cc04217h

M3 - Article

C2 - 26186554

AN - SCOPUS:84938844275

SN - 1359-7345

VL - 51

SP - 13094

EP - 13097

JO - Chemical Communications

JF - Chemical Communications

IS - 66

ER -

Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Abstract

Bibliographical note

Access to Document

Fingerprint

Cite this