Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Junying Chen; Kyung Bin Cho; Yong Min Lee; Yoon Hye Kwon; Wonwoo Nam

doi:10.1039/c5cc04217h

Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Junying Chen, Kyung Bin Cho, Yong Min Lee, Yoon Hye Kwon, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [M^IVO(N4Py)]²⁺ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that Fe^IVO is more reactive than Mn^IVO. The latter is shown to react through excited state reactivity (ESR).

Original language	English
Pages (from-to)	13094-13097
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	66
DOIs	https://doi.org/10.1039/c5cc04217h
State	Published - 25 Aug 2015

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© 2015 The Royal Society of Chemistry.

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title = "Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction",

abstract = "Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).",

author = "Junying Chen and Cho, {Kyung Bin} and Lee, {Yong Min} and Kwon, {Yoon Hye} and Wonwoo Nam",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "25",

doi = "10.1039/c5cc04217h",

language = "English",

volume = "51",

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publisher = "Royal Society of Chemistry",

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T1 - Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions

T2 - Experimental results prove theoretical prediction

AU - Chen, Junying

AU - Cho, Kyung Bin

AU - Lee, Yong Min

AU - Kwon, Yoon Hye

AU - Nam, Wonwoo

PY - 2015/8/25

Y1 - 2015/8/25

N2 - Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).

AB - Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).

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U2 - 10.1039/c5cc04217h

DO - 10.1039/c5cc04217h

M3 - Article

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AN - SCOPUS:84938844275

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SP - 13094

EP - 13097

JO - Chemical Communications

JF - Chemical Communications

IS - 66

ER -

Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Abstract

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