Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

Junying Chen, Kyung Bin Cho, Yong Min Lee, Yoon Hye Kwon, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that FeIVO is more reactive than MnIVO. The latter is shown to react through excited state reactivity (ESR).

Original languageEnglish
Pages (from-to)13094-13097
Number of pages4
JournalChemical Communications
Volume51
Issue number66
DOIs
StatePublished - 25 Aug 2015

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