Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Jamespandi Annaraj; Yumi Suh; Mi Sook Seo; Sun Ok Kim; Wonwoo Nam

doi:10.1039/b505562h

Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Jamespandi Annaraj, Yumi Suh, Mi Sook Seo, Sun Ok Kim, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe^III-O₂]₊, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe_II(TMC)] ²⁺, and molecular oxygen is reported as well.

Original language	English
Pages (from-to)	4529-4531
Number of pages	3
Journal	Chemical Communications
Issue number	36
DOIs	https://doi.org/10.1039/b505562h
State	Published - 28 Sep 2005

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title = "Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation",

abstract = "A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)FeIII-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [FeII(TMC)] 2+, and molecular oxygen is reported as well.",

author = "Jamespandi Annaraj and Yumi Suh and Seo, {Mi Sook} and Kim, {Sun Ok} and Wonwoo Nam",

year = "2005",

month = sep,

day = "28",

doi = "10.1039/b505562h",

language = "English",

pages = "4529--4531",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

AU - Annaraj, Jamespandi

AU - Suh, Yumi

AU - Seo, Mi Sook

AU - Kim, Sun Ok

AU - Nam, Wonwoo

PY - 2005/9/28

Y1 - 2005/9/28

N2 - A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)FeIII-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [FeII(TMC)] 2+, and molecular oxygen is reported as well.

AB - A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)FeIII-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [FeII(TMC)] 2+, and molecular oxygen is reported as well.

UR - http://www.scopus.com/inward/record.url?scp=26444553553&partnerID=8YFLogxK

U2 - 10.1039/b505562h

DO - 10.1039/b505562h

M3 - Article

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AN - SCOPUS:26444553553

SN - 1359-7345

SP - 4529

EP - 4531

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Abstract

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