Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Jamespandi Annaraj, Yumi Suh, Mi Sook Seo, Sun Ok Kim, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

74 Scopus citations

Abstract

A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)FeIII-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [FeII(TMC)] 2+, and molecular oxygen is reported as well.

Original languageEnglish
Pages (from-to)4529-4531
Number of pages3
JournalChemical Communications
Issue number36
DOIs
StatePublished - 28 Sep 2005

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