Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Shunichi Fukuzumi; Hiroaki Kotani; Heather R. Lucas; Kaoru Doi; Tomoyoshi Suenobu; Ryan L. Peterson; Kenneth D. Karlin

doi:10.1021/ja100538x

Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Shunichi Fukuzumi
, Hiroaki Kotani
, Heather R. Lucas
, Kaoru Doi
, Tomoyoshi Suenobu
, Ryan L. Peterson
, Kenneth D. Karlin

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

131 Scopus citations

Abstract

A mononuclear Cu^II complex acts as an efficient catalyst for four-electron reduction of O₂ to H₂O. Its reduction by a ferrocene derivative (Fc*) and reaction with O₂ leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the Cu^II complex.

Original language	English
Pages (from-to)	6874-6875
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	20
DOIs	https://doi.org/10.1021/ja100538x
State	Published - 26 May 2010

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title = "Mononuclear copper complex-catalyzed four-electron reduction of oxygen",

abstract = "A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.",

author = "Shunichi Fukuzumi and Hiroaki Kotani and Lucas, \{Heather R.\} and Kaoru Doi and Tomoyoshi Suenobu and Peterson, \{Ryan L.\} and Karlin, \{Kenneth D.\}",

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doi = "10.1021/ja100538x",

language = "English",

volume = "132",

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journal = "Journal of the American Chemical Society",

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T1 - Mononuclear copper complex-catalyzed four-electron reduction of oxygen

AU - Fukuzumi, Shunichi

AU - Kotani, Hiroaki

AU - Lucas, Heather R.

AU - Doi, Kaoru

AU - Suenobu, Tomoyoshi

AU - Peterson, Ryan L.

AU - Karlin, Kenneth D.

PY - 2010/5/26

Y1 - 2010/5/26

N2 - A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.

AB - A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.

UR - https://www.scopus.com/pages/publications/77952567658

U2 - 10.1021/ja100538x

DO - 10.1021/ja100538x

M3 - Article

C2 - 20443560

AN - SCOPUS:77952567658

SN - 0002-7863

VL - 132

SP - 6874

EP - 6875

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Abstract

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