Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Shunichi Fukuzumi; Hiroaki Kotani; Heather R. Lucas; Kaoru Doi; Tomoyoshi Suenobu; Ryan L. Peterson; Kenneth D. Karlin

doi:10.1021/ja100538x

Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Shunichi Fukuzumi, Hiroaki Kotani, Heather R. Lucas, Kaoru Doi, Tomoyoshi Suenobu, Ryan L. Peterson, Kenneth D. Karlin

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

129 Scopus citations

Abstract

A mononuclear Cu^II complex acts as an efficient catalyst for four-electron reduction of O₂ to H₂O. Its reduction by a ferrocene derivative (Fc*) and reaction with O₂ leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the Cu^II complex.

Original language	English
Pages (from-to)	6874-6875
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	20
DOIs	https://doi.org/10.1021/ja100538x
State	Published - 26 May 2010

Access to Document

10.1021/ja100538x

Cite this

@article{e4a28018b6d048cdaeb3a68338045927,

title = "Mononuclear copper complex-catalyzed four-electron reduction of oxygen",

abstract = "A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.",

author = "Shunichi Fukuzumi and Hiroaki Kotani and Lucas, \{Heather R.\} and Kaoru Doi and Tomoyoshi Suenobu and Peterson, \{Ryan L.\} and Karlin, \{Kenneth D.\}",

year = "2010",

month = may,

day = "26",

doi = "10.1021/ja100538x",

language = "English",

volume = "132",

pages = "6874--6875",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Mononuclear copper complex-catalyzed four-electron reduction of oxygen

AU - Fukuzumi, Shunichi

AU - Kotani, Hiroaki

AU - Lucas, Heather R.

AU - Doi, Kaoru

AU - Suenobu, Tomoyoshi

AU - Peterson, Ryan L.

AU - Karlin, Kenneth D.

PY - 2010/5/26

Y1 - 2010/5/26

N2 - A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.

AB - A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.

UR - https://www.scopus.com/pages/publications/77952567658

U2 - 10.1021/ja100538x

DO - 10.1021/ja100538x

M3 - Article

C2 - 20443560

AN - SCOPUS:77952567658

SN - 0002-7863

VL - 132

SP - 6874

EP - 6875

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Abstract

Access to Document

Fingerprint

Cite this