Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Shunichi Fukuzumi; Hiroaki Kotani; Heather R. Lucas; Kaoru Doi; Tomoyoshi Suenobu; Ryan L. Peterson; Kenneth D. Karlin

doi:10.1021/ja100538x

Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Shunichi Fukuzumi, Hiroaki Kotani, Heather R. Lucas, Kaoru Doi, Tomoyoshi Suenobu, Ryan L. Peterson, Kenneth D. Karlin

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

121 Scopus citations

Abstract

A mononuclear Cu^II complex acts as an efficient catalyst for four-electron reduction of O₂ to H₂O. Its reduction by a ferrocene derivative (Fc*) and reaction with O₂ leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the Cu^II complex.

Original language	English
Pages (from-to)	6874-6875
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	20
DOIs	https://doi.org/10.1021/ja100538x
State	Published - 26 May 2010

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title = "Mononuclear copper complex-catalyzed four-electron reduction of oxygen",

abstract = "A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.",

author = "Shunichi Fukuzumi and Hiroaki Kotani and Lucas, {Heather R.} and Kaoru Doi and Tomoyoshi Suenobu and Peterson, {Ryan L.} and Karlin, {Kenneth D.}",

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AU - Fukuzumi, Shunichi

AU - Kotani, Hiroaki

AU - Lucas, Heather R.

AU - Doi, Kaoru

AU - Suenobu, Tomoyoshi

AU - Peterson, Ryan L.

AU - Karlin, Kenneth D.

PY - 2010/5/26

Y1 - 2010/5/26

N2 - A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.

AB - A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex.

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U2 - 10.1021/ja100538x

DO - 10.1021/ja100538x

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AN - SCOPUS:77952567658

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SP - 6874

EP - 6875

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Abstract

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