Monolayer protected Au cluster (MPC)-bound Ru-carbene complex: Synthesis and its catalytic activity in ring-closing olefin metathesis

Sook Lee Bang, Keon Namgoong Sung, Sang Gi Lee

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Monolayer-protected gold cluster (Au-MPC)-bound Ru-carbene complex (MPC-7) has been synthesized and examined its catalytic activity in ring-closing olefin metathesis. The MPC-7 showed almost the same catalytic activity with that of simple molecules (Grubbs Ru-complex 1b and the thioacetate-functionalized Ru-complex 8) and reused several times.

Original languageEnglish
Pages (from-to)4501-4503
Number of pages3
JournalTetrahedron Letters
Volume46
Issue number26
DOIs
StatePublished - 27 Jun 2005

Keywords

  • Gold cluster
  • Metathesis
  • Monolayer
  • Ru-carbene complex

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