Model complexes for the active form of galactose oxidase. Physicochemical properties of Cu(II)- and Zn(II)-phenoxyl radical complexes

Shinobu Itoh; Masayasu Taki; Hideyuki Kumei; Shigehisa Takayama; Shigenori Nagatomo; Teizo Kitagawa; Norio Sakurada; Ryuichi Arakawa; Shunichi Fukuzumi

doi:10.1021/ic9910211

Model complexes for the active form of galactose oxidase. Physicochemical properties of Cu(II)- and Zn(II)-phenoxyl radical complexes

Shinobu Itoh
, Masayasu Taki
, Hideyuki Kumei
, Shigehisa Takayama
, Shigenori Nagatomo
, Teizo Kitagawa
, Norio Sakurada
, Ryuichi Arakawa
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Physicochemical properties of the Cu(II)- and Zn(II)-phenoxyl radical complexes of ligand 1H and its 2,4-di-tert-butyl derivative 2H have been examined as models for the active form of galactose oxidase to shed light on the role of the thioether group in the novel organic cofactor.

Original language	English
Pages (from-to)	3708-3711
Number of pages	4
Journal	Inorganic Chemistry
Volume	39
Issue number	16
DOIs	https://doi.org/10.1021/ic9910211
State	Published - 7 Aug 2000

Bibliographical note

Funding Information:
Supported by R01CA058420, UM1CA164974, and U01CA164974 from the National Cancer Institute.

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10.1021/ic9910211

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title = "Model complexes for the active form of galactose oxidase. Physicochemical properties of Cu(II)- and Zn(II)-phenoxyl radical complexes",

abstract = "Physicochemical properties of the Cu(II)- and Zn(II)-phenoxyl radical complexes of ligand 1H and its 2,4-di-tert-butyl derivative 2H have been examined as models for the active form of galactose oxidase to shed light on the role of the thioether group in the novel organic cofactor.",

author = "Shinobu Itoh and Masayasu Taki and Hideyuki Kumei and Shigehisa Takayama and Shigenori Nagatomo and Teizo Kitagawa and Norio Sakurada and Ryuichi Arakawa and Shunichi Fukuzumi",

note = "Funding Information: Supported by R01CA058420, UM1CA164974, and U01CA164974 from the National Cancer Institute.",

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doi = "10.1021/ic9910211",

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T1 - Model complexes for the active form of galactose oxidase. Physicochemical properties of Cu(II)- and Zn(II)-phenoxyl radical complexes

AU - Itoh, Shinobu

AU - Taki, Masayasu

AU - Kumei, Hideyuki

AU - Takayama, Shigehisa

AU - Nagatomo, Shigenori

AU - Kitagawa, Teizo

AU - Sakurada, Norio

AU - Arakawa, Ryuichi

AU - Fukuzumi, Shunichi

N1 - Funding Information: Supported by R01CA058420, UM1CA164974, and U01CA164974 from the National Cancer Institute.

PY - 2000/8/7

Y1 - 2000/8/7

N2 - Physicochemical properties of the Cu(II)- and Zn(II)-phenoxyl radical complexes of ligand 1H and its 2,4-di-tert-butyl derivative 2H have been examined as models for the active form of galactose oxidase to shed light on the role of the thioether group in the novel organic cofactor.

AB - Physicochemical properties of the Cu(II)- and Zn(II)-phenoxyl radical complexes of ligand 1H and its 2,4-di-tert-butyl derivative 2H have been examined as models for the active form of galactose oxidase to shed light on the role of the thioether group in the novel organic cofactor.

UR - https://www.scopus.com/pages/publications/0034617569

U2 - 10.1021/ic9910211

DO - 10.1021/ic9910211

M3 - Article

C2 - 11196837

AN - SCOPUS:0034617569

SN - 0020-1669

VL - 39

SP - 3708

EP - 3711

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

Model complexes for the active form of galactose oxidase. Physicochemical properties of Cu(II)- and Zn(II)-phenoxyl radical complexes

Abstract

Bibliographical note

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