[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand

Mi Sook Seo; Ja Young Kim; Jamespandi Annaraj; Youngmee Kim; Yong Min Lee; Sung Jin Kim; Jinheung Kim; Wonwoo Nam

doi:10.1002/anie.200603414

[Mn(tmc)(O₂)]⁺: A side-on peroxido manganese(III) complex bearing a non-heme ligand

Mi Sook Seo, Ja Young Kim, Jamespandi Annaraj, Youngmee Kim, Yong Min Lee, Sung Jin Kim, Jinheung Kim, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

123 Scopus citations

Abstract

(Chemical Equation Presented) On the side: The crystal structure of a peroxido Mn^III complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η² fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane.

Original language	English
Pages (from-to)	377-380
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	3
DOIs	https://doi.org/10.1002/anie.200603414
State	Published - 2007

Keywords

Aldehyde deformylation
Bioinorganic chemistry
Enzyme models
Manganese
O-O activation

Access to Document

10.1002/anie.200603414

Cite this

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abstract = "(Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane.",

keywords = "Aldehyde deformylation, Bioinorganic chemistry, Enzyme models, Manganese, O-O activation",

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T2 - A side-on peroxido manganese(III) complex bearing a non-heme ligand

AU - Seo, Mi Sook

AU - Kim, Ja Young

AU - Annaraj, Jamespandi

AU - Kim, Youngmee

AU - Lee, Yong Min

AU - Kim, Sung Jin

AU - Kim, Jinheung

AU - Nam, Wonwoo

PY - 2007

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AB - (Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane.

KW - Aldehyde deformylation

KW - Bioinorganic chemistry

KW - Enzyme models

KW - Manganese

KW - O-O activation

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