Abstract
(Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane.
Original language | English |
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Pages (from-to) | 377-380 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 46 |
Issue number | 3 |
DOIs | |
State | Published - 2007 |
Keywords
- Aldehyde deformylation
- Bioinorganic chemistry
- Enzyme models
- Manganese
- O-O activation