[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand

Mi Sook Seo, Ja Young Kim, Jamespandi Annaraj, Youngmee Kim, Yong Min Lee, Sung Jin Kim, Jinheung Kim, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

107 Scopus citations

Abstract

(Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane.

Original languageEnglish
Pages (from-to)377-380
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number3
DOIs
StatePublished - 2007

Keywords

  • Aldehyde deformylation
  • Bioinorganic chemistry
  • Enzyme models
  • Manganese
  • O-O activation

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