Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]

Youngmee Kim; Wonwoo Nam; Mi Hee Lim; Sook Won Jin; Alan J. Lough; Sung Jin Kim

doi:10.1107/S0108270101003006

Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH₃)]

Youngmee Kim, Wonwoo Nam, Mi Hee Lim, Sook Won Jin, Alan J. Lough, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The crystal structure of the title compound, [Fe(C₄₄H₂₀F₈N₄)- (CH₃O)], has been determined. The Fe atom lies 0.485 (1) ,Å out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) Å. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two C_por-C-C-C_ar systems.

Original language	English
Pages (from-to)	556-557
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	5
DOIs	https://doi.org/10.1107/S0108270101003006
State	Published - May 2001

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title = "Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]",

abstract = "The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe atom lies 0.485 (1) ,{\AA} out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) {\AA}. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two Cpor-C-C-Car systems.",

author = "Youngmee Kim and Wonwoo Nam and Lim, {Mi Hee} and Jin, {Sook Won} and Lough, {Alan J.} and Kim, {Sung Jin}",

year = "2001",

month = may,

doi = "10.1107/S0108270101003006",

language = "English",

volume = "57",

pages = "556--557",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "5",

}

TY - JOUR

T1 - Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]

AU - Kim, Youngmee

AU - Nam, Wonwoo

AU - Lim, Mi Hee

AU - Jin, Sook Won

AU - Lough, Alan J.

AU - Kim, Sung Jin

PY - 2001/5

Y1 - 2001/5

N2 - The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe atom lies 0.485 (1) ,Å out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) Å. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two Cpor-C-C-Car systems.

AB - The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe atom lies 0.485 (1) ,Å out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) Å. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two Cpor-C-C-Car systems.

UR - http://www.scopus.com/inward/record.url?scp=0035324551&partnerID=8YFLogxK

U2 - 10.1107/S0108270101003006

DO - 10.1107/S0108270101003006

M3 - Article

C2 - 11353248

AN - SCOPUS:0035324551

SN - 0108-2701

VL - 57

SP - 556

EP - 557

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 5

ER -

Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]

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Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH₃)]