Meso-Alkylidene (m-benzi)pentaphyrin: A modified pentaphyrin bearing exocyclic double bonds at meso-positions

Seung Doo Jeong; Agnieszka Nowak-Król; Youngmee Kim; Sung Jin Kim; Daniel T. Gryko; Chang Hee Lee

doi:10.1039/c0cc03263h

Meso-Alkylidene (m-benzi)pentaphyrin: A modified pentaphyrin bearing exocyclic double bonds at meso-positions

Seung Doo Jeong, Agnieszka Nowak-Król, Youngmee Kim, Sung Jin Kim, Daniel T. Gryko, Chang Hee Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

meso-Alkylidene (m-benzi)pentaphyrin containing exocyclic C=C double bonds at two meso-positions is synthesized and fully characterized for the first time. The single crystal X-ray crystallographic analysis shows a concave conformation with two pyrrole rings inverted. The first protonation occurs exclusively at core nitrogen. The synthesized compound displays concentration dependent chromogenic responses for fluoride anion in organic solvent.

Original language	English
Pages (from-to)	8737-8739
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	46
DOIs	https://doi.org/10.1039/c0cc03263h
State	Published - 14 Dec 2010

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title = "Meso-Alkylidene (m-benzi)pentaphyrin: A modified pentaphyrin bearing exocyclic double bonds at meso-positions",

abstract = "meso-Alkylidene (m-benzi)pentaphyrin containing exocyclic C=C double bonds at two meso-positions is synthesized and fully characterized for the first time. The single crystal X-ray crystallographic analysis shows a concave conformation with two pyrrole rings inverted. The first protonation occurs exclusively at core nitrogen. The synthesized compound displays concentration dependent chromogenic responses for fluoride anion in organic solvent.",

author = "Jeong, {Seung Doo} and Agnieszka Nowak-Kr{\'o}l and Youngmee Kim and Kim, {Sung Jin} and Gryko, {Daniel T.} and Lee, {Chang Hee}",

year = "2010",

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doi = "10.1039/c0cc03263h",

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T2 - A modified pentaphyrin bearing exocyclic double bonds at meso-positions

AU - Jeong, Seung Doo

AU - Nowak-Król, Agnieszka

AU - Kim, Youngmee

AU - Kim, Sung Jin

AU - Gryko, Daniel T.

AU - Lee, Chang Hee

PY - 2010/12/14

Y1 - 2010/12/14

N2 - meso-Alkylidene (m-benzi)pentaphyrin containing exocyclic C=C double bonds at two meso-positions is synthesized and fully characterized for the first time. The single crystal X-ray crystallographic analysis shows a concave conformation with two pyrrole rings inverted. The first protonation occurs exclusively at core nitrogen. The synthesized compound displays concentration dependent chromogenic responses for fluoride anion in organic solvent.

AB - meso-Alkylidene (m-benzi)pentaphyrin containing exocyclic C=C double bonds at two meso-positions is synthesized and fully characterized for the first time. The single crystal X-ray crystallographic analysis shows a concave conformation with two pyrrole rings inverted. The first protonation occurs exclusively at core nitrogen. The synthesized compound displays concentration dependent chromogenic responses for fluoride anion in organic solvent.

UR - http://www.scopus.com/inward/record.url?scp=78549254876&partnerID=8YFLogxK

U2 - 10.1039/c0cc03263h

DO - 10.1039/c0cc03263h

M3 - Article

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AN - SCOPUS:78549254876

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -

Meso-Alkylidene (m-benzi)pentaphyrin: A modified pentaphyrin bearing exocyclic double bonds at meso-positions

Abstract

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