Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)-oxo complex

Eunji Kwon; Kyung Bin Cho; Seungwoo Hong; Wonwoo Nam

doi:10.1039/c4cc01058b

Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(_v)-oxo complex

Eunji Kwon, Kyung Bin Cho, Seungwoo Hong, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

Hydroxylation of alkanes by a mononuclear nonheme iron(_v)-oxo complex, [Fe(_v)(O)(TAML)]⁻, is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.

Original language	English
Pages (from-to)	5572-5575
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	42
DOIs	https://doi.org/10.1039/c4cc01058b
State	Published - 29 Apr 2014

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title = "Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)-oxo complex",

abstract = "Hydroxylation of alkanes by a mononuclear nonheme iron(v)-oxo complex, [Fe(v)(O)(TAML)]−, is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.",

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AU - Kwon, Eunji

AU - Cho, Kyung Bin

AU - Hong, Seungwoo

AU - Nam, Wonwoo

PY - 2014/4/29

Y1 - 2014/4/29

N2 - Hydroxylation of alkanes by a mononuclear nonheme iron(v)-oxo complex, [Fe(v)(O)(TAML)]−, is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.

AB - Hydroxylation of alkanes by a mononuclear nonheme iron(v)-oxo complex, [Fe(v)(O)(TAML)]−, is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.

UR - https://www.scopus.com/pages/publications/84899626505

U2 - 10.1039/c4cc01058b

DO - 10.1039/c4cc01058b

M3 - Article

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VL - 50

SP - 5572

EP - 5575

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)-oxo complex

Abstract

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Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(_v)-oxo complex