Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands

Young Oh Na; Yumi Suh; Joo Park Mi; Sook Seo Mi; Jinheung Kim; Wonwoo Nam

doi:10.1002/anie.200500623

Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands

Young Oh Na, Yumi Suh, Joo Park Mi, Sook Seo Mi, Jinheung Kim, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

147 Scopus citations

Abstract

(Chemical Equation Presented) Iron-mediated oxidation: High-valent iron(IV)-oxo complexes of heme and nonheme ligands are generated in situ and are used in mechanistic studies of alcohol oxidation (see scheme). It is proposed that the oxidation of alcohols occurs by an α-CH hydrogen atom abstraction followed by electron transfer. Porp = porphyrin.

Original language	English
Pages (from-to)	4235-4239
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	27
DOIs	https://doi.org/10.1002/anie.200500623
State	Published - 4 Jul 2005

Keywords

Alcohols
Enzyme models
Iron
Oxidation
Reaction mechanisms

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10.1002/anie.200500623

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abstract = "(Chemical Equation Presented) Iron-mediated oxidation: High-valent iron(IV)-oxo complexes of heme and nonheme ligands are generated in situ and are used in mechanistic studies of alcohol oxidation (see scheme). It is proposed that the oxidation of alcohols occurs by an α-CH hydrogen atom abstraction followed by electron transfer. Porp = porphyrin.",

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AU - Kim, Jinheung

AU - Nam, Wonwoo

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KW - Alcohols

KW - Enzyme models

KW - Iron

KW - Oxidation

KW - Reaction mechanisms

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Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands

Abstract

Keywords

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