Manganese(v)-oxo corroles in hydride-transfer reactions

Yejee Han; Yong Min Lee; Mariappan Mariappan; Shunichi Fukuzumi; Wonwoo Nam

doi:10.1039/c0cc03373a

Manganese(v)-oxo corroles in hydride-transfer reactions

Yejee Han
, Yong Min Lee
, Mariappan Mariappan
, Shunichi Fukuzumi
, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E _red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

Original language	English
Pages (from-to)	8160-8162
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	43
DOIs	https://doi.org/10.1039/c0cc03373a
State	Published - 21 Nov 2010

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title = "Manganese(v)-oxo corroles in hydride-transfer reactions",

abstract = "Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.",

author = "Yejee Han and Lee, \{Yong Min\} and Mariappan Mariappan and Shunichi Fukuzumi and Wonwoo Nam",

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T1 - Manganese(v)-oxo corroles in hydride-transfer reactions

AU - Han, Yejee

AU - Lee, Yong Min

AU - Mariappan, Mariappan

AU - Fukuzumi, Shunichi

AU - Nam, Wonwoo

PY - 2010/11/21

Y1 - 2010/11/21

N2 - Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

AB - Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

UR - https://www.scopus.com/pages/publications/77958500853

U2 - 10.1039/c0cc03373a

DO - 10.1039/c0cc03373a

M3 - Article

C2 - 20936230

AN - SCOPUS:77958500853

SN - 1359-7345

VL - 46

SP - 8160

EP - 8162

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Manganese(v)-oxo corroles in hydride-transfer reactions

Abstract

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