Manganese(v)-oxo corroles in hydride-transfer reactions

Yejee Han, Yong Min Lee, Mariappan Mariappan, Shunichi Fukuzumi, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

Original languageEnglish
Pages (from-to)8160-8162
Number of pages3
JournalChemical Communications
Volume46
Issue number43
DOIs
StatePublished - 21 Nov 2010

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