Long-lived charge separation in a rigid pentiptycene bis(crown ether)–Li+C60 host–guest complex

Mustafa Supur; Yuki Kawashima; Ying Xian Ma; Kei Ohkubo; Chuan Feng Chen; Shunichi Fukuzumi

doi:10.1039/c4cc07795d

Long-lived charge separation in a rigid pentiptycene bis(crown ether)–Li⁺C₆₀ host–guest complex

Mustafa Supur, Yuki Kawashima, Ying Xian Ma, Kei Ohkubo, Chuan Feng Chen, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

We report long-lived charge separation in a highly rigid host–guest complex of pentiptycene bis(crown ether) and Li⁺@C₆₀, in which the pentiptycene framework is actively involved as an electron donor in a photoinduced electron-transfer process to the excited states of Li⁺@C₆₀ through a rigid distance in the complex.

Original language	English
Pages (from-to)	15796-15798
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	99
DOIs	https://doi.org/10.1039/c4cc07795d
State	Published - 18 Nov 2014

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abstract = "We report long-lived charge separation in a highly rigid host–guest complex of pentiptycene bis(crown ether) and Li+@C60, in which the pentiptycene framework is actively involved as an electron donor in a photoinduced electron-transfer process to the excited states of Li+@C60 through a rigid distance in the complex.",

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AU - Supur, Mustafa

AU - Kawashima, Yuki

AU - Ma, Ying Xian

AU - Ohkubo, Kei

AU - Chen, Chuan Feng

AU - Fukuzumi, Shunichi

PY - 2014/11/18

Y1 - 2014/11/18

N2 - We report long-lived charge separation in a highly rigid host–guest complex of pentiptycene bis(crown ether) and Li+@C60, in which the pentiptycene framework is actively involved as an electron donor in a photoinduced electron-transfer process to the excited states of Li+@C60 through a rigid distance in the complex.

AB - We report long-lived charge separation in a highly rigid host–guest complex of pentiptycene bis(crown ether) and Li+@C60, in which the pentiptycene framework is actively involved as an electron donor in a photoinduced electron-transfer process to the excited states of Li+@C60 through a rigid distance in the complex.

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EP - 15798

JO - Chemical Communications

JF - Chemical Communications

IS - 99

ER -

Long-lived charge separation in a rigid pentiptycene bis(crown ether)–Li+C60 host–guest complex

Abstract

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Long-lived charge separation in a rigid pentiptycene bis(crown ether)–Li⁺C₆₀ host–guest complex