Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

Ok Joo Lee; Valérie Maraval; Anne Marie Caminade; Kyungwha Chung; King Hang Aaron Lau; Kwanwoo Shin; Jean Pierre Majoral; Wolfgang Knoll; Dong Ha Kim

doi:10.1007/s13233-016-4128-z

Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

Ok Joo Lee
, Valérie Maraval
, Anne Marie Caminade
, Kyungwha Chung
, King Hang Aaron Lau
, Kwanwoo Shin
, Jean Pierre Majoral
, Wolfgang Knoll
, Dong Ha Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1^st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2^nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]

Original language	English
Pages (from-to)	851-855
Number of pages	5
Journal	Macromolecular Research
Volume	24
Issue number	10
DOIs	https://doi.org/10.1007/s13233-016-4128-z
State	Published - 1 Oct 2016

Bibliographical note

Publisher Copyright:
© 2016, The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht.

Keywords

bisdendron
layer-by-layer self-assembly
multilayer thin films
surface plasmon resonance spectroscopy

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10.1007/s13233-016-4128-z

Cite this

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title = "Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films",

abstract = "We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]",

keywords = "bisdendron, layer-by-layer self-assembly, multilayer thin films, surface plasmon resonance spectroscopy",

author = "Lee, \{Ok Joo\} and Val{\'e}rie Maraval and Caminade, \{Anne Marie\} and Kyungwha Chung and Lau, \{King Hang Aaron\} and Kwanwoo Shin and Majoral, \{Jean Pierre\} and Wolfgang Knoll and Kim, \{Dong Ha\}",

note = "Publisher Copyright: {\textcopyright} 2016, The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht.",

year = "2016",

month = oct,

day = "1",

doi = "10.1007/s13233-016-4128-z",

language = "English",

volume = "24",

pages = "851--855",

journal = "Macromolecular Research",

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publisher = "Polymer Society of Korea",

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TY - JOUR

T1 - Layer-by-layer self-assembly of bisdendrons

T2 - An unprecedented route to multilayer thin films

AU - Lee, Ok Joo

AU - Maraval, Valérie

AU - Caminade, Anne Marie

AU - Chung, Kyungwha

AU - Lau, King Hang Aaron

AU - Shin, Kwanwoo

AU - Majoral, Jean Pierre

AU - Knoll, Wolfgang

AU - Kim, Dong Ha

PY - 2016/10/1

Y1 - 2016/10/1

N2 - We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]

AB - We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]

KW - bisdendron

KW - layer-by-layer self-assembly

KW - multilayer thin films

KW - surface plasmon resonance spectroscopy

UR - https://www.scopus.com/pages/publications/84984820397

U2 - 10.1007/s13233-016-4128-z

DO - 10.1007/s13233-016-4128-z

M3 - Article

AN - SCOPUS:84984820397

SN - 1598-5032

VL - 24

SP - 851

EP - 855

JO - Macromolecular Research

JF - Macromolecular Research

IS - 10

ER -

Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

Abstract

Bibliographical note

Keywords

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