Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

Ok Joo Lee; Valérie Maraval; Anne Marie Caminade; Kyungwha Chung; King Hang Aaron Lau; Kwanwoo Shin; Jean Pierre Majoral; Wolfgang Knoll; Dong Ha Kim

doi:10.1007/s13233-016-4128-z

Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

Ok Joo Lee, Valérie Maraval, Anne Marie Caminade, Kyungwha Chung, King Hang Aaron Lau, Kwanwoo Shin, Jean Pierre Majoral, Wolfgang Knoll, Dong Ha Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1^st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2^nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]

Original language	English
Pages (from-to)	851-855
Number of pages	5
Journal	Macromolecular Research
Volume	24
Issue number	10
DOIs	https://doi.org/10.1007/s13233-016-4128-z
State	Published - 1 Oct 2016

Bibliographical note

Publisher Copyright:
© 2016, The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht.

Keywords

bisdendron
layer-by-layer self-assembly
multilayer thin films
surface plasmon resonance spectroscopy

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10.1007/s13233-016-4128-z

Cite this

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title = "Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films",

abstract = "We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]",

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doi = "10.1007/s13233-016-4128-z",

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T1 - Layer-by-layer self-assembly of bisdendrons

T2 - An unprecedented route to multilayer thin films

AU - Lee, Ok Joo

AU - Maraval, Valérie

AU - Caminade, Anne Marie

AU - Chung, Kyungwha

AU - Lau, King Hang Aaron

AU - Shin, Kwanwoo

AU - Majoral, Jean Pierre

AU - Knoll, Wolfgang

AU - Kim, Dong Ha

PY - 2016/10/1

Y1 - 2016/10/1

N2 - We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]

AB - We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.[Figure not available: see fulltext.]

KW - bisdendron

KW - layer-by-layer self-assembly

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KW - surface plasmon resonance spectroscopy

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Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

Abstract

Bibliographical note

Keywords

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