Large Polarization of Li4Ti5O12 Lithiated to 0 v at Large Charge/Discharge Rates

Cuiping Han, Yan Bing He, Shuan Wang, Chao Wang, Hongda Du, Xianying Qin, Zhiqun Lin, Baohua Li, Feiyu Kang

Research output: Contribution to journalArticlepeer-review

51 Scopus citations

Abstract

The ability to enhance the specific capacity of Li4Ti5O12 (LTO) is of practical significance and offers the opportunity to increase the energy density of a full LTO-based battery. Widening the discharge cutoff voltage to 0 V is an effective way to increase the capacity of LTO at low current density. However, whether the specific capacity of LTO at large current rates can be enhanced remains largely unknown. Herein, intriguingly, we found that, when cycled down to 0 V (i.e., from 1.0-2.5 to 0-25 V), LTO exhibited greatly enhanced specific capacity at low rates (<5 C), while it showed a rapid capacity fading and a greatly increased charge/discharge potential gap at high rates (>10 C). The decreased lithium-ion diffusion caused by extra lithium-ion intercalation together with increased internal impedance significantly enhances the polarization and reduces the electrochemical reaction kinetics, which, in turn, hinders the lithiation reaction from LTO to Li7Ti5O12 and further to Li9Ti5O12.

Original languageEnglish
Pages (from-to)18788-18796
Number of pages9
JournalACS Applied Materials and Interfaces
Volume8
Issue number29
DOIs
StatePublished - 27 Jul 2016

Bibliographical note

Publisher Copyright:
© 2016 American Chemical Society.

Keywords

  • anode
  • batteries
  • capacity
  • enhancement
  • voltage range

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