Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

Byeongno Lee; Seung Hee Kang; Donghyeon Kang; Kyu Hyung Lee; Jaeheung Cho; Wonwoo Nam; Oc Hee Han; Nam Hwi Hur

doi:10.1039/c1cc14542h

Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

Byeongno Lee, Seung Hee Kang, Donghyeon Kang, Kyu Hyung Lee, Jaeheung Cho, Wonwoo Nam, Oc Hee Han, Nam Hwi Hur

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO₂. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH₃ ⁺NHCO₂^-. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.

Original language	English
Pages (from-to)	11219-11221
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	40
DOIs	https://doi.org/10.1039/c1cc14542h
State	Published - 28 Oct 2011

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title = "Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide",

abstract = "A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO2. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH3 +NHCO2-. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.",

author = "Byeongno Lee and Kang, {Seung Hee} and Donghyeon Kang and Lee, {Kyu Hyung} and Jaeheung Cho and Wonwoo Nam and Han, {Oc Hee} and Hur, {Nam Hwi}",

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AU - Lee, Byeongno

AU - Kang, Seung Hee

AU - Kang, Donghyeon

AU - Lee, Kyu Hyung

AU - Cho, Jaeheung

AU - Nam, Wonwoo

AU - Han, Oc Hee

AU - Hur, Nam Hwi

PY - 2011/10/28

Y1 - 2011/10/28

N2 - A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO2. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH3 +NHCO2-. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.

AB - A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO2. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH3 +NHCO2-. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.

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DO - 10.1039/c1cc14542h

M3 - Article

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AN - SCOPUS:80053497354

SN - 1359-7345

VL - 47

SP - 11219

EP - 11221

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

Abstract

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