Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

Byeongno Lee, Seung Hee Kang, Donghyeon Kang, Kyu Hyung Lee, Jaeheung Cho, Wonwoo Nam, Oc Hee Han, Nam Hwi Hur

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO2. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH3 +NHCO2-. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.

Original languageEnglish
Pages (from-to)11219-11221
Number of pages3
JournalChemical Communications
Volume47
Issue number40
DOIs
StatePublished - 28 Oct 2011

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