Iridium-catalyzed C-H amination with anilines at room temperature: Compatibility of iridacycles with external oxidants

Hyunwoo Kim, Kwangmin Shin, Sukbok Chang

Research output: Contribution to journalArticlepeer-review

164 Scopus citations

Abstract

Described herein is the development of an iridium-catalyzed direct C-H amination of benzamides with anilines at room temperature, representing a unique example of an Ir catalyst system that is compatible with external oxidants. Mechanistic details, such as the isolation and characterization of key iridacycle intermediates, are also discussed.

Original languageEnglish
Pages (from-to)5904-5907
Number of pages4
JournalJournal of the American Chemical Society
Volume136
Issue number16
DOIs
StatePublished - 23 Apr 2014

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