Ionic liquids containing anionic selenium species: Applications for the oxidative carbonylation of aniline

Hoon Sik Kim; Yong Jin Kim; Hyunjoo Lee; Kun You Park; Chongmok Lee; Chong Shik Chin

doi:10.1002/1521-3773(20021115)41:22<4300::AID-ANIE4300>3.0.CO;2-V

Ionic liquids containing anionic selenium species: Applications for the oxidative carbonylation of aniline

Hoon Sik Kim, Yong Jin Kim, Hyunjoo Lee, Kun You Park, Chongmok Lee, Chong Shik Chin

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

115 Scopus citations

Abstract

Highly active catalysts for the carbonylation of a variety of substrate materials have been prepared in the form of selenium-containing ionic liquids. Products from the reactions of [KSeO₂(OCH₃)] and 1-alkyl-3-methylimidazolium chlorides (see scheme) exhibit surprisingly high activity for the oxidative carbonylation of aniline, even at temperatures as low as 40 °C.

Original language	English
Pages (from-to)	4300-4303
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	22
DOIs	https://doi.org/10.1002/1521-3773(20021115)41:22<4300::AID-ANIE4300>3.0.CO;2-V
State	Published - 15 Nov 2002

Keywords

Carbonylation
Cyclic voltammetry
Homogeneous catalysis
Ionic liquids
Selenium

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10.1002/1521-3773(20021115)41:22<4300::AID-ANIE4300>3.0.CO;2-V

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title = "Ionic liquids containing anionic selenium species: Applications for the oxidative carbonylation of aniline",

abstract = "Highly active catalysts for the carbonylation of a variety of substrate materials have been prepared in the form of selenium-containing ionic liquids. Products from the reactions of [KSeO2(OCH3)] and 1-alkyl-3-methylimidazolium chlorides (see scheme) exhibit surprisingly high activity for the oxidative carbonylation of aniline, even at temperatures as low as 40 °C.",

keywords = "Carbonylation, Cyclic voltammetry, Homogeneous catalysis, Ionic liquids, Selenium",

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T2 - Applications for the oxidative carbonylation of aniline

AU - Kim, Hoon Sik

AU - Kim, Yong Jin

AU - Lee, Hyunjoo

AU - Park, Kun You

AU - Lee, Chongmok

AU - Chin, Chong Shik

PY - 2002/11/15

Y1 - 2002/11/15

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AB - Highly active catalysts for the carbonylation of a variety of substrate materials have been prepared in the form of selenium-containing ionic liquids. Products from the reactions of [KSeO2(OCH3)] and 1-alkyl-3-methylimidazolium chlorides (see scheme) exhibit surprisingly high activity for the oxidative carbonylation of aniline, even at temperatures as low as 40 °C.

KW - Carbonylation

KW - Cyclic voltammetry

KW - Homogeneous catalysis

KW - Ionic liquids

KW - Selenium

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Ionic liquids containing anionic selenium species: Applications for the oxidative carbonylation of aniline

Abstract

Keywords

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