Ionic complexes based on the cluster anion [Re12CS 17(CN)6]6- and Cu2+ complex cations

Yu V. Mironov; Sung Jin Kim; V. E. Fedorov

doi:10.1007/s11172-008-0319-x

Ionic complexes based on the cluster anion [Re₁₂CS ₁₇(CN)₆]^6- and Cu²⁺ complex cations

Yu V. Mironov, Sung Jin Kim, V. E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The reactions of the dodecanuclear cluster anion [Re₁₂CS ₁₇(CN)₆]^6- with ammoniacal solutions of the divalent copper salts, CuCl₂ and Cu(en)₂Cl₂, were studied. Two new ionic compounds [Cu(NH₃)₅] ₃[Re₁₂CS₁₇(CN)₆]•8H ₂O (1) and Cu(NH₃)(en)₂][Cu(NH ₃)₃(en)]₂-[Re₁₂CS ₁₇(CN)₆]•5H₂O (2) were synthesized. The structures of both compounds were established by single-crystal X-ray diffraction.

Original language	English
Pages (from-to)	2271-2274
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	57
Issue number	11
DOIs	https://doi.org/10.1007/s11172-008-0319-x
State	Published - Nov 2008

Bibliographical note

Funding Information:
This study was financially supported by the Russian Foundation for Basic Research (Project No. 07 03 00912), the SRC of the Korea Science and Engineering Foundation (Grant No. R11 2005 008 000 0) and in the framework of the Russian Taiwan Joint Research Projects 06 03 89503 HHC and 95WFD0300050 (Contract No. RP06N02 2).

Keywords

Crystal structure
Dodecanuclear cluster
Rhenium
Synthesis

Access to Document

10.1007/s11172-008-0319-x

Cite this

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title = "Ionic complexes based on the cluster anion [Re12CS 17(CN)6]6- and Cu2+ complex cations",

abstract = "The reactions of the dodecanuclear cluster anion [Re12CS 17(CN)6]6- with ammoniacal solutions of the divalent copper salts, CuCl2 and Cu(en)2Cl2, were studied. Two new ionic compounds [Cu(NH3)5] 3[Re12CS17(CN)6]•8H 2O (1) and Cu(NH3)(en)2][Cu(NH 3)3(en)]2-[Re12CS 17(CN)6]•5H2O (2) were synthesized. The structures of both compounds were established by single-crystal X-ray diffraction.",

keywords = "Crystal structure, Dodecanuclear cluster, Rhenium, Synthesis",

author = "Mironov, {Yu V.} and Kim, {Sung Jin} and Fedorov, {V. E.}",

note = "Funding Information: This study was financially supported by the Russian Foundation for Basic Research (Project No. 07 03 00912), the SRC of the Korea Science and Engineering Foundation (Grant No. R11 2005 008 000 0) and in the framework of the Russian Taiwan Joint Research Projects 06 03 89503 HHC and 95WFD0300050 (Contract No. RP06N02 2).",

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doi = "10.1007/s11172-008-0319-x",

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T1 - Ionic complexes based on the cluster anion [Re12CS 17(CN)6]6- and Cu2+ complex cations

AU - Mironov, Yu V.

AU - Kim, Sung Jin

AU - Fedorov, V. E.

N1 - Funding Information: This study was financially supported by the Russian Foundation for Basic Research (Project No. 07 03 00912), the SRC of the Korea Science and Engineering Foundation (Grant No. R11 2005 008 000 0) and in the framework of the Russian Taiwan Joint Research Projects 06 03 89503 HHC and 95WFD0300050 (Contract No. RP06N02 2).

PY - 2008/11

Y1 - 2008/11

N2 - The reactions of the dodecanuclear cluster anion [Re12CS 17(CN)6]6- with ammoniacal solutions of the divalent copper salts, CuCl2 and Cu(en)2Cl2, were studied. Two new ionic compounds [Cu(NH3)5] 3[Re12CS17(CN)6]•8H 2O (1) and Cu(NH3)(en)2][Cu(NH 3)3(en)]2-[Re12CS 17(CN)6]•5H2O (2) were synthesized. The structures of both compounds were established by single-crystal X-ray diffraction.

AB - The reactions of the dodecanuclear cluster anion [Re12CS 17(CN)6]6- with ammoniacal solutions of the divalent copper salts, CuCl2 and Cu(en)2Cl2, were studied. Two new ionic compounds [Cu(NH3)5] 3[Re12CS17(CN)6]•8H 2O (1) and Cu(NH3)(en)2][Cu(NH 3)3(en)]2-[Re12CS 17(CN)6]•5H2O (2) were synthesized. The structures of both compounds were established by single-crystal X-ray diffraction.

KW - Crystal structure

KW - Dodecanuclear cluster

KW - Rhenium

KW - Synthesis

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