Abstract
The reactions of the dodecanuclear cluster anion [Re12CS 17(CN)6]6- with ammoniacal solutions of the divalent copper salts, CuCl2 and Cu(en)2Cl2, were studied. Two new ionic compounds [Cu(NH3)5] 3[Re12CS17(CN)6]•8H 2O (1) and Cu(NH3)(en)2][Cu(NH 3)3(en)]2-[Re12CS 17(CN)6]•5H2O (2) were synthesized. The structures of both compounds were established by single-crystal X-ray diffraction.
Original language | English |
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Pages (from-to) | 2271-2274 |
Number of pages | 4 |
Journal | Russian Chemical Bulletin |
Volume | 57 |
Issue number | 11 |
DOIs | |
State | Published - Nov 2008 |
Bibliographical note
Funding Information:This study was financially supported by the Russian Foundation for Basic Research (Project No. 07 03 00912), the SRC of the Korea Science and Engineering Foundation (Grant No. R11 2005 008 000 0) and in the framework of the Russian Taiwan Joint Research Projects 06 03 89503 HHC and 95WFD0300050 (Contract No. RP06N02 2).
Keywords
- Crystal structure
- Dodecanuclear cluster
- Rhenium
- Synthesis