Ionic CNT-supported Ru-carbene complex for recyclable ring-closing metathesis

Sujin Lee, Ju Yeon Shin, Sang Gi Lee

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The ionic multi-walled carbon nanotubes (IM-f-MWCNTs), which were covalently functionalized with imidazolium salt, have been utilized as support materials for the immobilization of Hoveyda-type Ru-carbene complex. The catalytic activity and recyclability of the ionic CNT-supported Ru-carbene complexes have been investigated for ring-closing metathesis of various dienes, and the recovered catalyst can be reused up to 10 times without any significant loss of catalytic activity.

Original languageEnglish
Pages (from-to)684-687
Number of pages4
JournalTetrahedron Letters
Volume54
Issue number7
DOIs
StatePublished - 13 Feb 2013

Keywords

  • Carbon nanotubes
  • Immobilization
  • Ionic liquid
  • Metathesis
  • Ruthenium-carbene complex

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