Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Yunkyung Jeong; Do Young Kim; Yunsil Choi; Jae Sang Ryu

doi:10.1039/c0ob00701c

Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Yunkyung Jeong, Do Young Kim, Yunsil Choi, Jae Sang Ryu

Department of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

The SO₃H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Brønsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.

Original language	English
Pages (from-to)	374-378
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	9
Issue number	2
DOIs	https://doi.org/10.1039/c0ob00701c
State	Published - 21 Jan 2011

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title = "Intramolecular hydroalkoxylation in Br{\o}nsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine",

abstract = "The SO3H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Br{\o}nsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.",

author = "Yunkyung Jeong and Kim, {Do Young} and Yunsil Choi and Ryu, {Jae Sang}",

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AU - Jeong, Yunkyung

AU - Kim, Do Young

AU - Choi, Yunsil

AU - Ryu, Jae Sang

PY - 2011/1/21

Y1 - 2011/1/21

N2 - The SO3H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Brønsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.

AB - The SO3H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Brønsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.

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U2 - 10.1039/c0ob00701c

DO - 10.1039/c0ob00701c

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AN - SCOPUS:78650752220

SN - 1477-0520

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EP - 378

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 2

ER -

Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Abstract

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