Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: An experimental and theoretical approach

Seungwoo Hong, Soo Jeong Jang, Kyung Bin Cho, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Oxygen atom transfer (OAT) reaction between an FeVO complex and a MnIII complex resulted in the eventual formation of their corresponding FeIII and MnVO complexes. The reaction proceeded via an initial fast OAT reaction between the FeVO and MnIII complexes, yielding a half equivalent of a MnVO complex and a μ-oxo bridged FeIV dimer. The dimer regenerated the FeVO species via equilibrium, which then reacted with the remaining MnIII complex to produce another half equivalent of the MnVO complex.

Original languageEnglish
Pages (from-to)12968-12971
Number of pages4
JournalChemical Communications
Volume52
Issue number88
DOIs
StatePublished - 2016

Bibliographical note

Publisher Copyright:
© The 2016 Royal Society of Chemistry.

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