Abstract
Oxygen atom transfer (OAT) reaction between an FeVO complex and a MnIII complex resulted in the eventual formation of their corresponding FeIII and MnVO complexes. The reaction proceeded via an initial fast OAT reaction between the FeVO and MnIII complexes, yielding a half equivalent of a MnVO complex and a μ-oxo bridged FeIV dimer. The dimer regenerated the FeVO species via equilibrium, which then reacted with the remaining MnIII complex to produce another half equivalent of the MnVO complex.
Original language | English |
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Pages (from-to) | 12968-12971 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 88 |
DOIs | |
State | Published - 2016 |
Bibliographical note
Publisher Copyright:© The 2016 Royal Society of Chemistry.