Instantaneous Colorimetric and Fluorogenic Detection of Phosgene with a meso-Oxime-BODIPY

Tae Il Kim, Byunghee Hwang, Jean Bouffard, Youngmi Kim

Research output: Contribution to journalArticlepeer-review

53 Scopus citations

Abstract

The meso-oxime-substituted-1,3,5,7-tetramethyl BODIPY (1-oxime) was developed into a colorimetric and fluorogenic probe to selectively detect and quantify phosgene. The fast (<10 s) and sensitive (LOD = 0.09 ppb) phosgene detection is achieved by the conversion of the meso-oxime to the meso-nitrile, resulting in a large fluorescence turn-on response. The utility of 1-oxime was established for the visual detection of phosgene in solution and in a practical solid-state platform, making it a suitable candidate for on-site monitoring of phosgene gas exposure in the workplace.

Original languageEnglish
Pages (from-to)12837-12842
Number of pages6
JournalAnalytical Chemistry
Volume89
Issue number23
DOIs
StatePublished - 5 Dec 2017

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