Insight into the role of charge carrier mediation zone for singlet oxygen production over rod-shape graphitic carbon nitride: Batch and continuous-flow reactor

As a new approach of creating the photo-exited electron (e^-) and hole (h⁺) mediation zone for highly selective singlet oxygen (¹O₂) production, the rod-type graphitic carbon nitride (NCN) has been synthesized from the nitric acid-modified melamine followed by the calcination. The NCN exhibited a higher surface area and surface oxygen adsorption ability than bulk graphitic carbon nitride (BCN). The increment of C[dbnd]O and NH_x groups on NCN corresponded to e^- and h⁺ mediation groups, respectively, resulting in higher production of ¹O₂ than BCN. Moreover, those mediation groups on NCN result in higher recombination efficiency and longer e^- decay time. As a result, the optimized NCN-0.5 (derived from 0.5 M of nitric acid-modified melamine) displayed 5.8 times higher kinetic rate constant of atrazine (ATZ) removal under UVA-LED irradiation compared to BCN. This study also evaluated the ATZ degradation pathways and toxicity effect of by-products. In addition, continuous flow experiments using NCN-0.5 showed superior ATZ removal performance with a hybrid concept between a slurry photocatalysis and a continuous stirred tank reactor system using actual effluent obtained from a wastewater treatment plant. Thus, this work provides an insight into the strategy for highly selective ¹O₂ production and the potential for water purification application.