Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Seung Hyun Chae; Kyung Yeon Lee; Sung Jin Kim; Suk Joong Lee; Youngmee Kim

doi:10.1016/j.inoche.2016.04.026

Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Seung Hyun Chae, Kyung Yeon Lee, Sung Jin Kim, Suk Joong Lee, Youngmee Kim

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)₂. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

Original language	English
Pages (from-to)	40-44
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	69
DOIs	https://doi.org/10.1016/j.inoche.2016.04.026
State	Published - 1 Jul 2016

Bibliographical note

Funding Information:
The authors acknowledge the financial supports from the Research Foundation Program ( NRF2013R1A1A2007429 , NRF20110020033 , NRF2015R1C1A2A01053025 ) and Key Research Institute Program ( NRF20100020209 ) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education. Appendix A

Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.

Keywords

Crystal
Molecular packing
Molecular platform
Morphology
Porphyrin

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10.1016/j.inoche.2016.04.026

Cite this

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title = "Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals",

abstract = "Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.",

keywords = "Crystal, Molecular packing, Molecular platform, Morphology, Porphyrin",

author = "Chae, {Seung Hyun} and Lee, {Kyung Yeon} and Kim, {Sung Jin} and Lee, {Suk Joong} and Youngmee Kim",

note = "Funding Information: The authors acknowledge the financial supports from the Research Foundation Program ( NRF2013R1A1A2007429 , NRF20110020033 , NRF2015R1C1A2A01053025 ) and Key Research Institute Program ( NRF20100020209 ) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education. Appendix A Publisher Copyright: {\textcopyright} 2016 Elsevier B.V. All rights reserved.",

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doi = "10.1016/j.inoche.2016.04.026",

language = "English",

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T1 - Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

AU - Chae, Seung Hyun

AU - Lee, Kyung Yeon

AU - Kim, Sung Jin

AU - Lee, Suk Joong

AU - Kim, Youngmee

N1 - Funding Information: The authors acknowledge the financial supports from the Research Foundation Program ( NRF2013R1A1A2007429 , NRF20110020033 , NRF2015R1C1A2A01053025 ) and Key Research Institute Program ( NRF20100020209 ) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education. Appendix A Publisher Copyright: © 2016 Elsevier B.V. All rights reserved.

PY - 2016/7/1

Y1 - 2016/7/1

N2 - Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

AB - Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

KW - Crystal

KW - Molecular packing

KW - Molecular platform

KW - Morphology

KW - Porphyrin

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U2 - 10.1016/j.inoche.2016.04.026

DO - 10.1016/j.inoche.2016.04.026

M3 - Article

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SN - 1387-7003

VL - 69

SP - 40

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Abstract

Bibliographical note

Keywords

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