TY - JOUR
T1 - Improvement of Open-Circuit Voltage Deficit via Pre-Treated NH4+ Ion Modification of Interface between SnO2 and Perovskite Solar Cells
AU - Kim, Jihyun
AU - Park, Joonho
AU - Kim, Yong Hoon
AU - Jo, William
N1 - Funding Information:
J.K. and J.P. contributed equally to this work. This study was supported by the Basic Science Research Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2018R1A6A1A03025340, NRF-2018R1D1A1B07049044, and NRF-2020R1I1A1A01068700), the Global Frontier R&D Program on the Center for Hybrid Interface Materials, the Basic Research Lab Program from Ministry of Science, Technology, ICT, and Future Planning (NRF-2021R1A2B5B02001961, 2013M3A6B1078884, 2020R1A4A2002806), the NRF grant from Korean government (NRF-2021R1A2B5B02002134), and the Samsung Research Funding & Incubation Center of Samsung Electronics (No. SRFC-TA2003-01). The computational resources were provided by the KISTI Supercomputing Center (KSC-2021-CRE-0322). [Correction added after publication 03 November 2022: A funding number was corrected to “2013M3A6B1078884”]
Funding Information:
J.K. and J.P. contributed equally to this work. This study was supported by the Basic Science Research Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF‐2018R1A6A1A03025340, NRF‐2018R1D1A1B07049044, and NRF‐2020R1I1A1A01068700), the Global Frontier R&D Program on the Center for Hybrid Interface Materials, the Basic Research Lab Program from Ministry of Science, Technology, ICT, and Future Planning (NRF‐2021R1A2B5B02001961, 2013M3A6B1078882, 2020R1A4A2002806), the NRF grant from Korean government (NRF‐2021R1A2B5B02002134), and the Samsung Research Funding & Incubation Center of Samsung Electronics (No. SRFC‐TA2003‐01). The computational resources were provided by the KISTI Supercomputing Center (KSC‐2021‐CRE‐0322).
Publisher Copyright:
© 2022 Wiley-VCH GmbH.
PY - 2022/11/3
Y1 - 2022/11/3
N2 - Passivation is a popular method to increase power conversion efficiency (PCE), reduce hysteresis related to surface traps and defects, and adjust mismatched energy levels. In this paper, an approach is reported using ammonium chloride (AC) to enhance passivation effects by controlling chlorine (Cl) and ammonium ions (NH4+) on the front and back side of tin oxides (SnO2). AC pre-treatment is applied to indium tin-oxide (ITO) prior to SnO2 deposition to advance the passivation approaches and compare the completely separated NH4+ and Cl passivation effects, and sole NH4+ is successfully isolated on the SnO2 surface, the counterpart of AC-post-treatment, generating ammonia (NH3) and Cl. It is demonstrated that multifunctional healing effects of NH4+ are ascribed from AC-pre-treatment being the basis of SnO2 crystallization and adjusting bifacial interface energy levels at ITO/SnO2 and SnO2/perovskite to enhance photo-carrier transport. As calculated by density functional theory, how the change of the passivation agent from Cl to NH4+ more effectively suppresses non-radiative recombination ascribed to hydrated SnO2 surface defects is explained. Consequently, enhancement of photo-carrier transport significantly improves a superior open-circuit voltage of 1.180 V and suppresses the hysteresis, which leads to the PCE of 22.25% in an AC-pre-treated device 3.000% higher than AC-post-treated devices.
AB - Passivation is a popular method to increase power conversion efficiency (PCE), reduce hysteresis related to surface traps and defects, and adjust mismatched energy levels. In this paper, an approach is reported using ammonium chloride (AC) to enhance passivation effects by controlling chlorine (Cl) and ammonium ions (NH4+) on the front and back side of tin oxides (SnO2). AC pre-treatment is applied to indium tin-oxide (ITO) prior to SnO2 deposition to advance the passivation approaches and compare the completely separated NH4+ and Cl passivation effects, and sole NH4+ is successfully isolated on the SnO2 surface, the counterpart of AC-post-treatment, generating ammonia (NH3) and Cl. It is demonstrated that multifunctional healing effects of NH4+ are ascribed from AC-pre-treatment being the basis of SnO2 crystallization and adjusting bifacial interface energy levels at ITO/SnO2 and SnO2/perovskite to enhance photo-carrier transport. As calculated by density functional theory, how the change of the passivation agent from Cl to NH4+ more effectively suppresses non-radiative recombination ascribed to hydrated SnO2 surface defects is explained. Consequently, enhancement of photo-carrier transport significantly improves a superior open-circuit voltage of 1.180 V and suppresses the hysteresis, which leads to the PCE of 22.25% in an AC-pre-treated device 3.000% higher than AC-post-treated devices.
KW - hysteresis
KW - interfacial passivation
KW - NH Cl pre-treatment
KW - open-circuit voltage
KW - perovskite solar cells
KW - photo-carrier dynamics
UR - http://www.scopus.com/inward/record.url?scp=85138634502&partnerID=8YFLogxK
U2 - 10.1002/smll.202204173
DO - 10.1002/smll.202204173
M3 - Article
C2 - 36161494
AN - SCOPUS:85138634502
SN - 1613-6810
VL - 18
JO - Small
JF - Small
IS - 44
M1 - 2204173
ER -