Hydrothermal synthesis of hollow SnO2 spheres with excellent electrochemical performance for anodes in lithium ion batteries

Ruiping Liu; Weiming Su; Chao Shen; James Iocozzia; Shiqiang Zhao; Kunjie Yuan; Ning Zhang; Chang an Wang; Zhiqun Lin

doi:10.1016/j.materresbull.2017.03.004

Hydrothermal synthesis of hollow SnO₂ spheres with excellent electrochemical performance for anodes in lithium ion batteries

Ruiping Liu
, Weiming Su
, Chao Shen
, James Iocozzia
, Shiqiang Zhao
, Kunjie Yuan
, Ning Zhang
, Chang an Wang
, Zhiqun Lin

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Hollow SnO₂ spheres with oriented cone-like SnO₂ nanoparticle shells were synthesized by a one-step hydrothermal process using NaF as the morphology controlling agent. The resulting hollow SnO₂ sphere electrode exhibits high reversible capacity (initial charge and discharge capacities of 1342.9 and 1947.6 mAh/g at 0.1 C and 1235.4 and 1741.3 mAh/g at 1 C) and good cycling stability (discharge capacities maintained 758.1 and 449.6 mAh/g after 100 cycles at 0.1 C and 1 C, respectively). Good rate performance was also obtained (1234.5 mAh/g at 0.1 C, 884.2 mAh/g at 0.2 C, 692.4 mAh/g at 0.5 C, 497.6 mAh/g at 1 C, 315.8 mAh/g at 2 C and 80.6 mAh/g at 5 C, and more importantly, when the current density returns to 0.1 C, a capacity of 869.6 mAh/g can be recovered. The observed electrochemical performance can attributed to the hollow structure, the use of NaF for morphology control and the unique oriented cone-like shell of the particles.

Original language	English
Pages (from-to)	443-448
Number of pages	6
Journal	Materials Research Bulletin
Volume	96
DOIs	https://doi.org/10.1016/j.materresbull.2017.03.004
State	Published - Dec 2017

Bibliographical note

Funding Information:
This work was supported by the National Natural Science Foundation of China (NSFC–No. 51202117 and 51572145 ), Natural Science Foundation of Beijing (No. 2162037 ), the Beijing Nova program (Z171100001117077) and Beijing outstanding talent (No. 2015000020124G121 ), the Fundamental Research Funds for the Central Universities (No. 2014QJ02 ) and the State key laboratory of Coal Resources and Safe Mining (No. SKLCRSM16KFB04 ).

Publisher Copyright:
© 2017 Elsevier Ltd

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Electrochemical properties
Oxides
Solvothermal

Access to Document

10.1016/j.materresbull.2017.03.004

Cite this

@article{a110c454b3b541809e807cee6e60006b,

title = "Hydrothermal synthesis of hollow SnO2 spheres with excellent electrochemical performance for anodes in lithium ion batteries",

abstract = "Hollow SnO2 spheres with oriented cone-like SnO2 nanoparticle shells were synthesized by a one-step hydrothermal process using NaF as the morphology controlling agent. The resulting hollow SnO2 sphere electrode exhibits high reversible capacity (initial charge and discharge capacities of 1342.9 and 1947.6 mAh/g at 0.1 C and 1235.4 and 1741.3 mAh/g at 1 C) and good cycling stability (discharge capacities maintained 758.1 and 449.6 mAh/g after 100 cycles at 0.1 C and 1 C, respectively). Good rate performance was also obtained (1234.5 mAh/g at 0.1 C, 884.2 mAh/g at 0.2 C, 692.4 mAh/g at 0.5 C, 497.6 mAh/g at 1 C, 315.8 mAh/g at 2 C and 80.6 mAh/g at 5 C, and more importantly, when the current density returns to 0.1 C, a capacity of 869.6 mAh/g can be recovered. The observed electrochemical performance can attributed to the hollow structure, the use of NaF for morphology control and the unique oriented cone-like shell of the particles.",

keywords = "Electrochemical properties, Oxides, Solvothermal",

author = "Ruiping Liu and Weiming Su and Chao Shen and James Iocozzia and Shiqiang Zhao and Kunjie Yuan and Ning Zhang and Wang, \{Chang an\} and Zhiqun Lin",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (NSFC–No. 51202117 and 51572145 ), Natural Science Foundation of Beijing (No. 2162037 ), the Beijing Nova program (Z171100001117077) and Beijing outstanding talent (No. 2015000020124G121 ), the Fundamental Research Funds for the Central Universities (No. 2014QJ02 ) and the State key laboratory of Coal Resources and Safe Mining (No. SKLCRSM16KFB04 ). Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

month = dec,

doi = "10.1016/j.materresbull.2017.03.004",

language = "English",

volume = "96",

pages = "443--448",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Hydrothermal synthesis of hollow SnO2 spheres with excellent electrochemical performance for anodes in lithium ion batteries

AU - Liu, Ruiping

AU - Su, Weiming

AU - Shen, Chao

AU - Iocozzia, James

AU - Zhao, Shiqiang

AU - Yuan, Kunjie

AU - Zhang, Ning

AU - Wang, Chang an

AU - Lin, Zhiqun

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (NSFC–No. 51202117 and 51572145 ), Natural Science Foundation of Beijing (No. 2162037 ), the Beijing Nova program (Z171100001117077) and Beijing outstanding talent (No. 2015000020124G121 ), the Fundamental Research Funds for the Central Universities (No. 2014QJ02 ) and the State key laboratory of Coal Resources and Safe Mining (No. SKLCRSM16KFB04 ). Publisher Copyright: © 2017 Elsevier Ltd

PY - 2017/12

Y1 - 2017/12

N2 - Hollow SnO2 spheres with oriented cone-like SnO2 nanoparticle shells were synthesized by a one-step hydrothermal process using NaF as the morphology controlling agent. The resulting hollow SnO2 sphere electrode exhibits high reversible capacity (initial charge and discharge capacities of 1342.9 and 1947.6 mAh/g at 0.1 C and 1235.4 and 1741.3 mAh/g at 1 C) and good cycling stability (discharge capacities maintained 758.1 and 449.6 mAh/g after 100 cycles at 0.1 C and 1 C, respectively). Good rate performance was also obtained (1234.5 mAh/g at 0.1 C, 884.2 mAh/g at 0.2 C, 692.4 mAh/g at 0.5 C, 497.6 mAh/g at 1 C, 315.8 mAh/g at 2 C and 80.6 mAh/g at 5 C, and more importantly, when the current density returns to 0.1 C, a capacity of 869.6 mAh/g can be recovered. The observed electrochemical performance can attributed to the hollow structure, the use of NaF for morphology control and the unique oriented cone-like shell of the particles.

AB - Hollow SnO2 spheres with oriented cone-like SnO2 nanoparticle shells were synthesized by a one-step hydrothermal process using NaF as the morphology controlling agent. The resulting hollow SnO2 sphere electrode exhibits high reversible capacity (initial charge and discharge capacities of 1342.9 and 1947.6 mAh/g at 0.1 C and 1235.4 and 1741.3 mAh/g at 1 C) and good cycling stability (discharge capacities maintained 758.1 and 449.6 mAh/g after 100 cycles at 0.1 C and 1 C, respectively). Good rate performance was also obtained (1234.5 mAh/g at 0.1 C, 884.2 mAh/g at 0.2 C, 692.4 mAh/g at 0.5 C, 497.6 mAh/g at 1 C, 315.8 mAh/g at 2 C and 80.6 mAh/g at 5 C, and more importantly, when the current density returns to 0.1 C, a capacity of 869.6 mAh/g can be recovered. The observed electrochemical performance can attributed to the hollow structure, the use of NaF for morphology control and the unique oriented cone-like shell of the particles.

KW - Electrochemical properties

KW - Oxides

KW - Solvothermal

UR - https://www.scopus.com/pages/publications/85015052358

U2 - 10.1016/j.materresbull.2017.03.004

DO - 10.1016/j.materresbull.2017.03.004

M3 - Article

AN - SCOPUS:85015052358

SN - 0025-5408

VL - 96

SP - 443

EP - 448

JO - Materials Research Bulletin

JF - Materials Research Bulletin

ER -