Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer

Heejung Yoon, Yong Min Lee, Wonwoo Nam, Shunichi Fukuzumi

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Hydride transfer from NADH analogues to a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the MnIV(O) complex and NADH analogues is involved in the hydride transfer reaction.

Original languageEnglish
Pages (from-to)12944-12946
Number of pages3
JournalChemical Communications
Volume50
Issue number85
DOIs
StatePublished - 30 Sep 2014

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