Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer

Heejung Yoon; Yong Min Lee; Wonwoo Nam; Shunichi Fukuzumi

doi:10.1039/c4cc05313c

Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer

Heejung Yoon, Yong Min Lee, Wonwoo Nam, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Hydride transfer from NADH analogues to a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)Mn^IV(O)]²⁺, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the Mn^IV(O) complex and NADH analogues is involved in the hydride transfer reaction.

Original language	English
Pages (from-to)	12944-12946
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	85
DOIs	https://doi.org/10.1039/c4cc05313c
State	Published - 30 Sep 2014

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title = "Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer",

abstract = "Hydride transfer from NADH analogues to a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the MnIV(O) complex and NADH analogues is involved in the hydride transfer reaction.",

author = "Heejung Yoon and Lee, {Yong Min} and Wonwoo Nam and Shunichi Fukuzumi",

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T1 - Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer

AU - Yoon, Heejung

AU - Lee, Yong Min

AU - Nam, Wonwoo

AU - Fukuzumi, Shunichi

PY - 2014/9/30

Y1 - 2014/9/30

N2 - Hydride transfer from NADH analogues to a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the MnIV(O) complex and NADH analogues is involved in the hydride transfer reaction.

AB - Hydride transfer from NADH analogues to a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the MnIV(O) complex and NADH analogues is involved in the hydride transfer reaction.

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U2 - 10.1039/c4cc05313c

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M3 - Article

C2 - 25220234

AN - SCOPUS:84907651755

SN - 1359-7345

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EP - 12946

JO - Chemical Communications

JF - Chemical Communications

IS - 85

ER -

Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer

Abstract

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