@article{85de50580ec14406b96280f4ea60348e,
title = "Highly stereoselective formation of optically pure 2,4-oxazolidinedione via diastereoselective dihydroxylation of (4S)-3-((E)-3′-substituted-2′-propenoyl)-4-isopropyl-2-oxazolidinone",
abstract = "Catalytic asymmetric dihydroxylation (ADH) of (4S)-3-((E)-3′-substituted-2′-propenoyl)-4-isopropyl-2-oxazolidinone1a and 1b resulted in the in situ rearrangement of the initially produced diols or its osmates to provide 3-((1'S)-1′-isopropyl-2′-hydroxyethyl)-5-(S)-5-((1'R)-1′-hydroxybenzyl (2a) and -hydroxyethyl (2b))-2,4-oxazolidinedione, respectively. The structure of 2a was determined by X-ray crystal structure analysis.",
author = "Song, {Choong Eui} and Roh, {Eun Joo} and Lee, {Sang gi} and Kim, {In O.}",
note = "Funding Information: Nevertheless, formation of 2 is efficient and highly stereoselective and suggest interesting possibilities for the asymmetric synthesis of a variety of chiral 3,5-disubstituted-2,4-oxazolidinedione derivatives. Some of 3,5-disubstituted-2,4-oxazolidinedione derivatives show fungicidal or pharmaceutical activities. 6) Acknowledgement: We are grateful to Korea Institut of Science and Technology (E-12980) for financial support.",
year = "1995",
month = apr,
doi = "10.1016/0957-4166(95)00092-4",
language = "English",
volume = "6",
pages = "871--872",
journal = "Tetrahedron Asymmetry",
issn = "0957-4166",
publisher = "Elsevier Ltd.",
number = "4",
}