Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions

Seungwoo Hong; Bin Wang; Mi Sook Seo; Yong Min Lee; Myoung Jin Kim; Hyung Rok Kim; Takashi Ogura; Ricardo Garcia-Serres; Martin Clémancey; Jean Marc Latour; Wonwoo Nam

doi:10.1002/anie.201402537

Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions

Seungwoo Hong, Bin Wang, Mi Sook Seo, Yong Min Lee, Myoung Jin Kim, Hyung Rok Kim, Takashi Ogura, Ricardo Garcia-Serres, Martin Clémancey, Jean Marc Latour, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

High-spin iron(III) iodosylarene complexes bearing an N-methylated cyclam ligand are synthesized and characterized using various spectroscopic methods. The nonheme high-spin iron(III) iodosylarene intermediates are highly reactive oxidants capable of activating strong C-H bonds of alkanes; the reactivity of the iron(III) iodosylarene intermediates is much greater than that of the corresponding iron(IV) oxo complex. The electrophilic character of the iron(III) iodosylarene complexes is demonstrated in sulfoxidation reactions.

Original language	English
Pages (from-to)	6388-6392
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	25
DOIs	https://doi.org/10.1002/anie.201402537
State	Published - 16 Jun 2014

Keywords

alkane hydroxylation
bioinorganic chemistry
enzyme models
nonheme iron complexes
sulfoxidation

Access to Document

10.1002/anie.201402537

Cite this

@article{fcdf58cc80694393b6db67b0f6e17a6b,

title = "Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions",

abstract = "High-spin iron(III) iodosylarene complexes bearing an N-methylated cyclam ligand are synthesized and characterized using various spectroscopic methods. The nonheme high-spin iron(III) iodosylarene intermediates are highly reactive oxidants capable of activating strong C-H bonds of alkanes; the reactivity of the iron(III) iodosylarene intermediates is much greater than that of the corresponding iron(IV) oxo complex. The electrophilic character of the iron(III) iodosylarene complexes is demonstrated in sulfoxidation reactions.",

keywords = "alkane hydroxylation, bioinorganic chemistry, enzyme models, nonheme iron complexes, sulfoxidation",

author = "Seungwoo Hong and Bin Wang and Seo, {Mi Sook} and Lee, {Yong Min} and Kim, {Myoung Jin} and Kim, {Hyung Rok} and Takashi Ogura and Ricardo Garcia-Serres and Martin Cl{\'e}mancey and Latour, {Jean Marc} and Wonwoo Nam",

year = "2014",

month = jun,

day = "16",

doi = "10.1002/anie.201402537",

language = "English",

volume = "53",

pages = "6388--6392",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "25",

}

TY - JOUR

T1 - Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions

AU - Hong, Seungwoo

AU - Wang, Bin

AU - Seo, Mi Sook

AU - Lee, Yong Min

AU - Kim, Myoung Jin

AU - Kim, Hyung Rok

AU - Ogura, Takashi

AU - Garcia-Serres, Ricardo

AU - Clémancey, Martin

AU - Latour, Jean Marc

AU - Nam, Wonwoo

PY - 2014/6/16

Y1 - 2014/6/16

N2 - High-spin iron(III) iodosylarene complexes bearing an N-methylated cyclam ligand are synthesized and characterized using various spectroscopic methods. The nonheme high-spin iron(III) iodosylarene intermediates are highly reactive oxidants capable of activating strong C-H bonds of alkanes; the reactivity of the iron(III) iodosylarene intermediates is much greater than that of the corresponding iron(IV) oxo complex. The electrophilic character of the iron(III) iodosylarene complexes is demonstrated in sulfoxidation reactions.

AB - High-spin iron(III) iodosylarene complexes bearing an N-methylated cyclam ligand are synthesized and characterized using various spectroscopic methods. The nonheme high-spin iron(III) iodosylarene intermediates are highly reactive oxidants capable of activating strong C-H bonds of alkanes; the reactivity of the iron(III) iodosylarene intermediates is much greater than that of the corresponding iron(IV) oxo complex. The electrophilic character of the iron(III) iodosylarene complexes is demonstrated in sulfoxidation reactions.

KW - alkane hydroxylation

KW - bioinorganic chemistry

KW - enzyme models

KW - nonheme iron complexes

KW - sulfoxidation

UR - http://www.scopus.com/inward/record.url?scp=84902274682&partnerID=8YFLogxK

U2 - 10.1002/anie.201402537

DO - 10.1002/anie.201402537

M3 - Article

C2 - 24820976

AN - SCOPUS:84902274682

SN - 1433-7851

VL - 53

SP - 6388

EP - 6392

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 25

ER -

Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions

Abstract

Keywords

Access to Document

Fingerprint

Cite this