Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization

Nara Kim; Seyoung Kee; Seoung Ho Lee; Byoung Hoon Lee; Yung Ho Kahng; Yong Ryun Jo; Bong Joong Kim; Kwanghee Lee

doi:10.1002/adma.201304611

Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization

Nara Kim, Seyoung Kee, Seoung Ho Lee, Byoung Hoon Lee, Yung Ho Kahng, Yong Ryun Jo, Bong Joong Kim, Kwanghee Lee

Department of Chemical Engineering & Materials Science

Research output: Contribution to journal › Article › peer-review

916 Scopus citations

Abstract

Crystalline poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanofibrils with an electrical conductivity of 4380 S cm ^-1 are formed via a solution process using H₂SO ₄. The concentrated H₂SO₄ treatment induces a significant structural rearrangement of the PEDOT:PSS via a charge-separated transition mechanism, resulting in highly ordered and densely packed PEDOT:PSS nanofibrils. The PEDOT:PSS electrode shows a sheet resistance of 46 Ω sq^-1 with 90% optical transmittance.

Original language	English
Pages (from-to)	2268-2272
Number of pages	5
Journal	Advanced Materials
Volume	26
Issue number	14
DOIs	https://doi.org/10.1002/adma.201304611
State	Published - 9 Apr 2014

Keywords

PEDOT:PSS
nanofibrils
organic electronics
solution-processed crystallization
transparent electrodes

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title = "Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization",

abstract = "Crystalline poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanofibrils with an electrical conductivity of 4380 S cm -1 are formed via a solution process using H2SO 4. The concentrated H2SO4 treatment induces a significant structural rearrangement of the PEDOT:PSS via a charge-separated transition mechanism, resulting in highly ordered and densely packed PEDOT:PSS nanofibrils. The PEDOT:PSS electrode shows a sheet resistance of 46 Ω sq-1 with 90% optical transmittance.",

keywords = "PEDOT:PSS, nanofibrils, organic electronics, solution-processed crystallization, transparent electrodes",

author = "Nara Kim and Seyoung Kee and Lee, {Seoung Ho} and Lee, {Byoung Hoon} and Kahng, {Yung Ho} and Jo, {Yong Ryun} and Kim, {Bong Joong} and Kwanghee Lee",

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T1 - Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization

AU - Kim, Nara

AU - Kee, Seyoung

AU - Lee, Seoung Ho

AU - Lee, Byoung Hoon

AU - Kahng, Yung Ho

AU - Jo, Yong Ryun

AU - Kim, Bong Joong

AU - Lee, Kwanghee

PY - 2014/4/9

Y1 - 2014/4/9

N2 - Crystalline poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanofibrils with an electrical conductivity of 4380 S cm -1 are formed via a solution process using H2SO 4. The concentrated H2SO4 treatment induces a significant structural rearrangement of the PEDOT:PSS via a charge-separated transition mechanism, resulting in highly ordered and densely packed PEDOT:PSS nanofibrils. The PEDOT:PSS electrode shows a sheet resistance of 46 Ω sq-1 with 90% optical transmittance.

AB - Crystalline poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanofibrils with an electrical conductivity of 4380 S cm -1 are formed via a solution process using H2SO 4. The concentrated H2SO4 treatment induces a significant structural rearrangement of the PEDOT:PSS via a charge-separated transition mechanism, resulting in highly ordered and densely packed PEDOT:PSS nanofibrils. The PEDOT:PSS electrode shows a sheet resistance of 46 Ω sq-1 with 90% optical transmittance.

KW - PEDOT:PSS

KW - nanofibrils

KW - organic electronics

KW - solution-processed crystallization

KW - transparent electrodes

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DO - 10.1002/adma.201304611

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VL - 26

SP - 2268

EP - 2272

JO - Advanced Materials

JF - Advanced Materials

IS - 14

ER -

Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization

Abstract

Keywords

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