Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Choong Eui Song; Jung Woon Yang; Eun Joo Roh; Sang Gi Lee; Jou Hyeon Ahn; Hogyu Han

doi:10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Choong Eui Song, Jung Woon Yang, Eun Joo Roh, Sang Gi Lee, Jou Hyeon Ahn, Hogyu Han

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η³-C₃H₅)PdCl}₂] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

Original language	English
Pages (from-to)	3852-3854
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	20
DOIs	https://doi.org/10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I
State	Published - 18 Oct 2002

Keywords

Asymmetric catalysis
Heterogeneous catalysis
P ligands
Palladium
Polymers

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10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

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abstract = "Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).",

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AU - Song, Choong Eui

AU - Yang, Jung Woon

AU - Roh, Eun Joo

AU - Lee, Sang Gi

AU - Ahn, Jou Hyeon

AU - Han, Hogyu

PY - 2002/10/18

Y1 - 2002/10/18

N2 - Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

AB - Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

KW - Asymmetric catalysis

KW - Heterogeneous catalysis

KW - P ligands

KW - Palladium

KW - Polymers

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JO - Angewandte Chemie - International Edition

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Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Abstract

Keywords

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