Green-Light-Driven Fe(III)(btz)3Photocatalysis in the Radical Cationic [4+2] Cycloaddition Reaction

Yu Jeong Jang, Hyeju An, Seunghee Choi, Jayeon Hong, Seung Hyun Lee, Kwang Hyun Ahn, Youngmin You, Eun Joo Kang

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Green-light-driven FeIII(btz)3photocatalysis for the radical cationic [4+2] cycloaddition of terminal styrenes and nucleophilic dienes has been investigated. The Fe-MIC (mesoionic carbene) complex forms a ligand-to-metal charge-transfer transition state with relatively high excited-state reduction potentials that can selectively oxidize terminal styrene derivatives. Unique multisubstituted cyclohexenes and structurally complex biorelevant cyclohexenes were constructed, highlighting the usefulness of this mild and practical first-row transition metal complex system.

Original languageEnglish
Pages (from-to)4479-4484
Number of pages6
JournalOrganic Letters
Volume24
Issue number24
DOIs
StatePublished - 24 Jun 2022

Bibliographical note

Funding Information:
This study was supported by the Ministry of Education, Science and Technology, National Research Foundation (NRF-2021R1A4A1030449, NRF-2021R1A2C1013993, NRF-2015M3D1A1070639, and NRF-2019R1A2C2003969), and the GRRC program of Gyeonggi province [GRRC-kyunghee2017(A01)].

Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.

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