Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

Kei Ohkubo, Javier Ortiz, Luis Martín-Gomis, Fernando Fernández-Lázaro, Ángela Sastre-Santos, Shunichi Fukuzumi

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

A long-lived charge-separated (CS) state of fullerene-trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C60 to TNF in the presence of Sc(OTf)3; the CS lifetime is determined as 23 ms in PhCN at 298 K.

Original languageEnglish
Pages (from-to)589-591
Number of pages3
JournalChemical Communications
Issue number6
DOIs
StatePublished - 2007

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