Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

Kei Ohkubo; Javier Ortiz; Luis Martín-Gomis; Fernando Fernández-Lázaro; Ángela Sastre-Santos; Shunichi Fukuzumi

doi:10.1039/b612613h

Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

Kei Ohkubo, Javier Ortiz, Luis Martín-Gomis, Fernando Fernández-Lázaro, Ángela Sastre-Santos, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A long-lived charge-separated (CS) state of fullerene-trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C₆₀ to TNF in the presence of Sc(OTf)₃; the CS lifetime is determined as 23 ms in PhCN at 298 K.

Original language	English
Pages (from-to)	589-591
Number of pages	3
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/b612613h
State	Published - 2007

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title = "Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion",

abstract = "A long-lived charge-separated (CS) state of fullerene-trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C60 to TNF in the presence of Sc(OTf)3; the CS lifetime is determined as 23 ms in PhCN at 298 K.",

author = "Kei Ohkubo and Javier Ortiz and Luis Mart{\'i}n-Gomis and Fernando Fern{\'a}ndez-L{\'a}zaro and {\'A}ngela Sastre-Santos and Shunichi Fukuzumi",

year = "2007",

doi = "10.1039/b612613h",

language = "English",

pages = "589--591",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "6",

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T1 - Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

AU - Ohkubo, Kei

AU - Ortiz, Javier

AU - Martín-Gomis, Luis

AU - Fernández-Lázaro, Fernando

AU - Sastre-Santos, Ángela

AU - Fukuzumi, Shunichi

PY - 2007

Y1 - 2007

N2 - A long-lived charge-separated (CS) state of fullerene-trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C60 to TNF in the presence of Sc(OTf)3; the CS lifetime is determined as 23 ms in PhCN at 298 K.

AB - A long-lived charge-separated (CS) state of fullerene-trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C60 to TNF in the presence of Sc(OTf)3; the CS lifetime is determined as 23 ms in PhCN at 298 K.

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U2 - 10.1039/b612613h

DO - 10.1039/b612613h

M3 - Article

AN - SCOPUS:33846838990

SN - 1359-7345

SP - 589

EP - 591

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

Abstract

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