From Precision Synthesis of Block Copolymers to Properties and Applications of Nanoparticles

Xiao Li, James Iocozzia, Yihuang Chen, Shiqiang Zhao, Xun Cui, Wei Wang, Haifeng Yu, Shaoliang Lin, Zhiqun Lin

Research output: Contribution to journalReview articlepeer-review

139 Scopus citations


Inorganic nanoparticles have become a research focus in numerous fields because of their unique properties that distinguish them from their bulk counterparts. Controlling the size and shape of nanoparticles is an essential aspect of nanoparticle synthesis. Preparing inorganic nanoparticles by using block copolymer templates is one of the most reliable routes for tuning the size and shape of nanoparticles with a high degree of precision. In this Review, we discuss recent progress in the design of block copolymer templates for crafting spherical inorganic nanoparticles including compact, hollow, and core–shell varieties. The templates are divided into two categories: micelles self-assembled from linear block copolymers and unimolecular star-shaped block copolymers. The precise control over the size and morphology of nanoparticles is highlighted as well as the useful properties and applications of such inorganic nanoparticles.

Original languageEnglish
Pages (from-to)2046-2070
Number of pages25
JournalAngewandte Chemie - International Edition
Issue number8
StatePublished - 19 Feb 2018

Bibliographical note

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim


  • core–shell structures
  • linear block copolymers
  • nanoparticles
  • nanoreactors
  • star-shaped block copolymers


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