Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water

Shunichi Fukuzumi; Takeshi Kobayashi; Tomoyoshi Suenobu

doi:10.1021/ja104486h

Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water

Shunichi Fukuzumi, Takeshi Kobayashi, Tomoyoshi Suenobu

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A heterodinuclear iridium-ruthenium complex [Ir^III(Cp*) (H₂O)(bpm)Ru^II(bpy)₂](SO₄) ₂ (Cp* = φ⁵-pentamethyl-cyclopentadienyl, bpm = 2,2′-bipyrimidine, bpy = 2,2′-bipyridine) acts as an effective catalyst for removal of dissolved O₂ by the four-electron reduction of O₂ with formic acid in water at an ambient temperature.

Original language	English
Pages (from-to)	11866-11867
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	34
DOIs	https://doi.org/10.1021/ja104486h
State	Published - 1 Sep 2010

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title = "Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water",

abstract = "A heterodinuclear iridium-ruthenium complex [IrIII(Cp*) (H2O)(bpm)RuII(bpy)2](SO4) 2 (Cp* = φ5-pentamethyl-cyclopentadienyl, bpm = 2,2′-bipyrimidine, bpy = 2,2′-bipyridine) acts as an effective catalyst for removal of dissolved O2 by the four-electron reduction of O2 with formic acid in water at an ambient temperature.",

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Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water. / Fukuzumi, Shunichi; Kobayashi, Takeshi; Suenobu, Tomoyoshi.
In: Journal of the American Chemical Society, Vol. 132, No. 34, 01.09.2010, p. 11866-11867.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water

AU - Fukuzumi, Shunichi

AU - Kobayashi, Takeshi

AU - Suenobu, Tomoyoshi

PY - 2010/9/1

Y1 - 2010/9/1

N2 - A heterodinuclear iridium-ruthenium complex [IrIII(Cp*) (H2O)(bpm)RuII(bpy)2](SO4) 2 (Cp* = φ5-pentamethyl-cyclopentadienyl, bpm = 2,2′-bipyrimidine, bpy = 2,2′-bipyridine) acts as an effective catalyst for removal of dissolved O2 by the four-electron reduction of O2 with formic acid in water at an ambient temperature.

AB - A heterodinuclear iridium-ruthenium complex [IrIII(Cp*) (H2O)(bpm)RuII(bpy)2](SO4) 2 (Cp* = φ5-pentamethyl-cyclopentadienyl, bpm = 2,2′-bipyrimidine, bpy = 2,2′-bipyridine) acts as an effective catalyst for removal of dissolved O2 by the four-electron reduction of O2 with formic acid in water at an ambient temperature.

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U2 - 10.1021/ja104486h

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 34

ER -

Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water

Abstract

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