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Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

  • Chivukula V. Sastri
  • , Mi Sook Seo
  • , Mi Joo Park
  • , Kwan Mook Kim
  • , Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

98 Scopus citations

Abstract

A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

Original languageEnglish
Pages (from-to)1405-1407
Number of pages3
JournalChemical Communications
Issue number11
DOIs
StatePublished - 21 Mar 2005

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