Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

Chivukula V. Sastri; Mi Sook Seo; Mi Joo Park; Kwan Mook Kim; Wonwoo Nam

doi:10.1039/b415507f

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

Chivukula V. Sastri, Mi Sook Seo, Mi Joo Park, Kwan Mook Kim, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

Original language	English
Pages (from-to)	1405-1407
Number of pages	3
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/b415507f
State	Published - 21 Mar 2005

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title = "Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution",

abstract = "A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.",

author = "Sastri, {Chivukula V.} and Seo, {Mi Sook} and Park, {Mi Joo} and Kim, {Kwan Mook} and Wonwoo Nam",

year = "2005",

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AU - Sastri, Chivukula V.

AU - Seo, Mi Sook

AU - Park, Mi Joo

AU - Kim, Kwan Mook

AU - Nam, Wonwoo

PY - 2005/3/21

Y1 - 2005/3/21

N2 - A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

AB - A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

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U2 - 10.1039/b415507f

DO - 10.1039/b415507f

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SP - 1405

EP - 1407

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

Abstract

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