Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin

Takahiko Kojima; Kakeru Hanabusa; Kei Ohkubo; Motoo Shiro; Shunichi Fukuzumi

doi:10.1039/b816063e

Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin

Takahiko Kojima
, Kakeru Hanabusa
, Kei Ohkubo
, Motoo Shiro
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl₂ to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of π-cation radical in the course of electrochemical oxidation.

Original language	English
Pages (from-to)	6513-6515
Number of pages	3
Journal	Chemical Communications
Issue number	48
DOIs	https://doi.org/10.1039/b816063e
State	Published - 2008

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title = "Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin",

abstract = "A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl2 to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of π-cation radical in the course of electrochemical oxidation.",

author = "Takahiko Kojima and Kakeru Hanabusa and Kei Ohkubo and Motoo Shiro and Shunichi Fukuzumi",

year = "2008",

doi = "10.1039/b816063e",

language = "English",

pages = "6513--6515",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin

AU - Kojima, Takahiko

AU - Hanabusa, Kakeru

AU - Ohkubo, Kei

AU - Shiro, Motoo

AU - Fukuzumi, Shunichi

PY - 2008

Y1 - 2008

N2 - A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl2 to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of π-cation radical in the course of electrochemical oxidation.

AB - A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl2 to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of π-cation radical in the course of electrochemical oxidation.

UR - https://www.scopus.com/pages/publications/57249094065

U2 - 10.1039/b816063e

DO - 10.1039/b816063e

M3 - Article

C2 - 19057763

AN - SCOPUS:57249094065

SN - 1359-7345

SP - 6513

EP - 6515

JO - Chemical Communications

JF - Chemical Communications

IS - 48

ER -

Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin

Abstract

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