TY - JOUR
T1 - Formation of a transient radial ion pair in the reactions of 1,5-dihydroflavin with hydride acceptors
AU - Ishikawa, Masashi
AU - Yamamoto, Kazuhiko
AU - Fukuzumi, Shunichi
PY - 1992
Y1 - 1992
N2 - The formation of a transient radical ion pair has been detected directly in the reactions of 1,5-dihydroriboflavin-2′,3′,4′,5′- tetraacetate (FlH2) with hydride acceptors (tetracyano-p- quinodimethane, tetracyanoethylene and p-benzoquinone derivatives) in deaerated acetonitrile, providing unequivocal evidence for an electron transfer pathway in the overall two-electron redox reactions of FlH2 with hydride acceptors.
AB - The formation of a transient radical ion pair has been detected directly in the reactions of 1,5-dihydroriboflavin-2′,3′,4′,5′- tetraacetate (FlH2) with hydride acceptors (tetracyano-p- quinodimethane, tetracyanoethylene and p-benzoquinone derivatives) in deaerated acetonitrile, providing unequivocal evidence for an electron transfer pathway in the overall two-electron redox reactions of FlH2 with hydride acceptors.
UR - http://www.scopus.com/inward/record.url?scp=37049072553&partnerID=8YFLogxK
U2 - 10.1039/C39920001008
DO - 10.1039/C39920001008
M3 - Article
AN - SCOPUS:37049072553
SN - 0022-4936
SP - 1008
EP - 1009
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 14
ER -