Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion

Kei Ohkubo; Javier Ortiz; Luis Martin-Gomis; Fernando Fernández-Lázaro; Ángela Sastre-Santos; Shunichi Fukuzumi

doi:10.1149/1.2408949

Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion

Kei Ohkubo, Javier Ortiz, Luis Martin-Gomis, Fernando Fernández-Lázaro, Ángela Sastre-Santos, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

A long-lived charge-separated state of fullerene-trinitrofluorenone linked dyad (C₆₀-TNF) is formed in the presence of Sc(OTf)₃ via intramolecular electron transfer from the singlet excited state of fullerene to TNF and binding of Sc³⁺ to the resulting TNF radical anion. The lifetime of the charge-separated state is determined as 23 ms in PhCN at 298 K. Copyright The Electrochemical Society.

Original language	English
Title of host publication	Fullerenes, Nanotubes, and Carbon Nanostructures
Publisher	Electrochemical Society Inc.
Pages	15-25
Number of pages	11
Edition	12
ISBN (Print)	9781566775236
DOIs	https://doi.org/10.1149/1.2408949
State	Published - 2006
Event	209th ECS Meeting - Denver, CO, United States Duration: 7 May 2006 → 12 May 2006

Publication series

Name	ECS Transactions
Number	12
Volume	2
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Conference

Conference	209th ECS Meeting
Country/Territory	United States
City	Denver, CO
Period	7/05/06 → 12/05/06

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10.1149/1.2408949

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Ohkubo, K., Ortiz, J., Martin-Gomis, L., Fernández-Lázaro, F., Sastre-Santos, Á., & Fukuzumi, S. (2006). Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion. In Fullerenes, Nanotubes, and Carbon Nanostructures (12 ed., pp. 15-25). (ECS Transactions; Vol. 2, No. 12). Electrochemical Society Inc.. https://doi.org/10.1149/1.2408949

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title = "Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion",

abstract = "A long-lived charge-separated state of fullerene-trinitrofluorenone linked dyad (C60-TNF) is formed in the presence of Sc(OTf)3 via intramolecular electron transfer from the singlet excited state of fullerene to TNF and binding of Sc3+ to the resulting TNF radical anion. The lifetime of the charge-separated state is determined as 23 ms in PhCN at 298 K. Copyright The Electrochemical Society.",

author = "Kei Ohkubo and Javier Ortiz and Luis Martin-Gomis and Fernando Fern{\'a}ndez-L{\'a}zaro and {\'A}ngela Sastre-Santos and Shunichi Fukuzumi",

year = "2006",

doi = "10.1149/1.2408949",

language = "English",

isbn = "9781566775236",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "12",

pages = "15--25",

booktitle = "Fullerenes, Nanotubes, and Carbon Nanostructures",

edition = "12",

note = "209th ECS Meeting ; Conference date: 07-05-2006 Through 12-05-2006",

}

Ohkubo, K, Ortiz, J, Martin-Gomis, L, Fernández-Lázaro, F, Sastre-Santos, Á & Fukuzumi, S 2006, Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion. in Fullerenes, Nanotubes, and Carbon Nanostructures. 12 edn, ECS Transactions, no. 12, vol. 2, Electrochemical Society Inc., pp. 15-25, 209th ECS Meeting, Denver, CO, United States, 7/05/06. https://doi.org/10.1149/1.2408949

Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion. / Ohkubo, Kei; Ortiz, Javier; Martin-Gomis, Luis et al.
Fullerenes, Nanotubes, and Carbon Nanostructures. 12. ed. Electrochemical Society Inc., 2006. p. 15-25 (ECS Transactions; Vol. 2, No. 12).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion

AU - Ohkubo, Kei

AU - Ortiz, Javier

AU - Martin-Gomis, Luis

AU - Fernández-Lázaro, Fernando

AU - Sastre-Santos, Ángela

AU - Fukuzumi, Shunichi

PY - 2006

Y1 - 2006

N2 - A long-lived charge-separated state of fullerene-trinitrofluorenone linked dyad (C60-TNF) is formed in the presence of Sc(OTf)3 via intramolecular electron transfer from the singlet excited state of fullerene to TNF and binding of Sc3+ to the resulting TNF radical anion. The lifetime of the charge-separated state is determined as 23 ms in PhCN at 298 K. Copyright The Electrochemical Society.

AB - A long-lived charge-separated state of fullerene-trinitrofluorenone linked dyad (C60-TNF) is formed in the presence of Sc(OTf)3 via intramolecular electron transfer from the singlet excited state of fullerene to TNF and binding of Sc3+ to the resulting TNF radical anion. The lifetime of the charge-separated state is determined as 23 ms in PhCN at 298 K. Copyright The Electrochemical Society.

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T3 - ECS Transactions

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BT - Fullerenes, Nanotubes, and Carbon Nanostructures

PB - Electrochemical Society Inc.

T2 - 209th ECS Meeting

Y2 - 7 May 2006 through 12 May 2006

ER -

Formation of a charge-separated state of a fullerene-trinitrofluorenone dyad by complexation with scandium ion

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