Fluorescent dye containing phenol-pyridyl for selective detection of aluminum ions

Jungha Lee; Hyun Kim; Soojin Kim; Jin Young Noh; Eun Joo Song; Cheal Kim; Jinheung Kim

doi:10.1016/j.dyepig.2012.10.008

Fluorescent dye containing phenol-pyridyl for selective detection of aluminum ions

Jungha Lee, Hyun Kim, Soojin Kim, Jin Young Noh, Eun Joo Song, Cheal Kim, Jinheung Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

120 Scopus citations

Abstract

A phenol-pyridylimine probe was utilized as an optical sensor to quantify the presence of aluminum ions using a turn-on fluorescence enhancement approach. The high sensitivity was the result of FRET amplification of the receptor subunit fluorescence emission. The complex stability constant (K_s) for the stoichiometric 1:1 complex of the sensor with aluminum ions was obtained by fluorimetric titration. Remarkably, fluorescence output was not significantly affected by other trivalent cations, particularly Ga³⁺ and In³⁺.

Original language	English
Pages (from-to)	590-594
Number of pages	5
Journal	Dyes and Pigments
Volume	96
Issue number	2
DOIs	https://doi.org/10.1016/j.dyepig.2012.10.008
State	Published - Feb 2013

Bibliographical note

Funding Information:
This work is supported by the National Research Foundation of Korea Grant funded by the Korean Government ( 2009-0087304 , 2010-0009525 , 2012008875 , 2012001725 , SRC Program: 2012-0000648), Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2011K000675 ), and BK21 (to J.L. and S.K.).

Keywords

Aluminum ion sensing
Fluorescent chemosensor
Phenol
Pyridyl
Selective binding
Turn-on detection

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10.1016/j.dyepig.2012.10.008

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title = "Fluorescent dye containing phenol-pyridyl for selective detection of aluminum ions",

abstract = "A phenol-pyridylimine probe was utilized as an optical sensor to quantify the presence of aluminum ions using a turn-on fluorescence enhancement approach. The high sensitivity was the result of FRET amplification of the receptor subunit fluorescence emission. The complex stability constant (Ks) for the stoichiometric 1:1 complex of the sensor with aluminum ions was obtained by fluorimetric titration. Remarkably, fluorescence output was not significantly affected by other trivalent cations, particularly Ga3+ and In3+.",

keywords = "Aluminum ion sensing, Fluorescent chemosensor, Phenol, Pyridyl, Selective binding, Turn-on detection",

author = "Jungha Lee and Hyun Kim and Soojin Kim and Noh, {Jin Young} and Song, {Eun Joo} and Cheal Kim and Jinheung Kim",

note = "Funding Information: This work is supported by the National Research Foundation of Korea Grant funded by the Korean Government ( 2009-0087304 , 2010-0009525 , 2012008875 , 2012001725 , SRC Program: 2012-0000648), Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2011K000675 ), and BK21 (to J.L. and S.K.). ",

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doi = "10.1016/j.dyepig.2012.10.008",

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AU - Lee, Jungha

AU - Kim, Hyun

AU - Kim, Soojin

AU - Noh, Jin Young

AU - Song, Eun Joo

AU - Kim, Cheal

AU - Kim, Jinheung

N1 - Funding Information: This work is supported by the National Research Foundation of Korea Grant funded by the Korean Government ( 2009-0087304 , 2010-0009525 , 2012008875 , 2012001725 , SRC Program: 2012-0000648), Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2011K000675 ), and BK21 (to J.L. and S.K.).

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N2 - A phenol-pyridylimine probe was utilized as an optical sensor to quantify the presence of aluminum ions using a turn-on fluorescence enhancement approach. The high sensitivity was the result of FRET amplification of the receptor subunit fluorescence emission. The complex stability constant (Ks) for the stoichiometric 1:1 complex of the sensor with aluminum ions was obtained by fluorimetric titration. Remarkably, fluorescence output was not significantly affected by other trivalent cations, particularly Ga3+ and In3+.

AB - A phenol-pyridylimine probe was utilized as an optical sensor to quantify the presence of aluminum ions using a turn-on fluorescence enhancement approach. The high sensitivity was the result of FRET amplification of the receptor subunit fluorescence emission. The complex stability constant (Ks) for the stoichiometric 1:1 complex of the sensor with aluminum ions was obtained by fluorimetric titration. Remarkably, fluorescence output was not significantly affected by other trivalent cations, particularly Ga3+ and In3+.

KW - Aluminum ion sensing

KW - Fluorescent chemosensor

KW - Phenol

KW - Pyridyl

KW - Selective binding

KW - Turn-on detection

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DO - 10.1016/j.dyepig.2012.10.008

M3 - Article

AN - SCOPUS:84868642015

SN - 0143-7208

VL - 96

SP - 590

EP - 594

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 2

ER -

Fluorescent dye containing phenol-pyridyl for selective detection of aluminum ions

Abstract

Bibliographical note

Keywords

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