First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6-

Yu V. Mironov; N. G. Naumov; Sung Jin Kim; V. E. Fedorov

doi:10.1134/S1070328407040070

First examples of cyano-bridged complexes based on a novel cluster anion [Re₁₂C₁₇(CN)₆]^6-

Yu V. Mironov, N. G. Naumov, Sung Jin Kim, V. E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re ₁₂CS₁₇(CN)₆] with Ni²⁺ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH ₃)₄} {Ni(NH₃)₅}₂Re ₁₂CS₁₇(CN)₆] · 7H₂O (I) with a chain structure and [Ni(NH₃)₆]₃[{Ni(NH ₃)₄}₃ {Re₁₂CS₁₇(CN) ₆}₂] · 21H₂O (II), containing the anionic dimeric complex [{Ni(NH₃)₄}₃ {Re ₁₂CS₁₇(CN)₆}₂]^6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å³, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å³, Z = 3.

Original language	English
Pages (from-to)	279-285
Number of pages	7
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	33
Issue number	4
DOIs	https://doi.org/10.1134/S1070328407040070
State	Published - Apr 2007

Bibliographical note

Funding Information:
This work was supported by the Russian Foundation for Basic Research (projects nos. 05-03-32123 and 05-03-08090), State Contract 02.442.11.7414, and International Cooperative Research Program of the Ministry of Science and Technology of Korea (project no. M60403000099-04A0100-02310).

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10.1134/S1070328407040070

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@article{0a7e56192ba14caab1efb91e4b8fd280,

title = "First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6-",

abstract = "Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re 12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH 3)4} {Ni(NH3)5}2Re 12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH 3)4}3 {Re12CS17(CN) 6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re 12CS17(CN)6}2]6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) {\AA}, β = 100.242(3)°, V = 2942.8(8) {\AA}3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) {\AA}, V = 9798.6(12) {\AA}3, Z = 3.",

author = "Mironov, {Yu V.} and Naumov, {N. G.} and Kim, {Sung Jin} and Fedorov, {V. E.}",

note = "Funding Information: This work was supported by the Russian Foundation for Basic Research (projects nos. 05-03-32123 and 05-03-08090), State Contract 02.442.11.7414, and International Cooperative Research Program of the Ministry of Science and Technology of Korea (project no. M60403000099-04A0100-02310).",

year = "2007",

month = apr,

doi = "10.1134/S1070328407040070",

language = "English",

volume = "33",

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T1 - First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6-

AU - Mironov, Yu V.

AU - Naumov, N. G.

AU - Kim, Sung Jin

AU - Fedorov, V. E.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research (projects nos. 05-03-32123 and 05-03-08090), State Contract 02.442.11.7414, and International Cooperative Research Program of the Ministry of Science and Technology of Korea (project no. M60403000099-04A0100-02310).

PY - 2007/4

Y1 - 2007/4

N2 - Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re 12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH 3)4} {Ni(NH3)5}2Re 12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH 3)4}3 {Re12CS17(CN) 6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re 12CS17(CN)6}2]6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å3, Z = 3.

AB - Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re 12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH 3)4} {Ni(NH3)5}2Re 12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH 3)4}3 {Re12CS17(CN) 6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re 12CS17(CN)6}2]6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å3, Z = 3.

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