TY - JOUR
T1 - First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6-
AU - Mironov, Yu V.
AU - Naumov, N. G.
AU - Kim, Sung Jin
AU - Fedorov, V. E.
N1 - Funding Information:
This work was supported by the Russian Foundation for Basic Research (projects nos. 05-03-32123 and 05-03-08090), State Contract 02.442.11.7414, and International Cooperative Research Program of the Ministry of Science and Technology of Korea (project no. M60403000099-04A0100-02310).
PY - 2007/4
Y1 - 2007/4
N2 - Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re 12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH 3)4} {Ni(NH3)5}2Re 12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH 3)4}3 {Re12CS17(CN) 6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re 12CS17(CN)6}2]6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å3, Z = 3.
AB - Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re 12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH 3)4} {Ni(NH3)5}2Re 12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH 3)4}3 {Re12CS17(CN) 6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re 12CS17(CN)6}2]6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å3, Z = 3.
UR - http://www.scopus.com/inward/record.url?scp=34247344056&partnerID=8YFLogxK
U2 - 10.1134/S1070328407040070
DO - 10.1134/S1070328407040070
M3 - Article
AN - SCOPUS:34247344056
SN - 1070-3284
VL - 33
SP - 279
EP - 285
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
IS - 4
ER -